Materials Map

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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

The dashboard provides detailed information about the selected scientist, e.g. publications. The dashboard can be filtered and shows the relationship to co-authors in different diagrams. In addition, a link is provided to find contact information.

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Topics

Publications (78/78 displayed)

  • 2024Structure and bonding in TiNiSi type LaMgSnH intermetallic hydride4citations
  • 2024Structure and bonding in TiNiSi type LaMgSnH intermetallic hydride4citations
  • 2024On the Ytterbium Valence and the Physical Properties in Selected Intermetallic Phasescitations
  • 2024The germanides Sc<i>T</i>Ge<sub>2</sub> (<i>T</i> = Fe, Co, Ru, Rh) – crystal chemistry, <sup>45</sup>Sc solid-state NMR and <sup>57</sup>Fe Mössbauer spectroscopycitations
  • 2024Synthesis and characterization of mullite‐type Sn(Cr1-xVx)BO4: Structural, vibrational, magnetic, and thermal propertiescitations
  • 2023MAl4Ir2 (M = Ca, Sr, Eu): superstructures of the KAu4In2 type1citations
  • 2023SrMg<sub>2</sub>Ga<sub>2</sub> with ThCr<sub>2</sub>Si<sub>2</sub>-type structurecitations
  • 2023Trivalent europium – a scarce case in intermetallics12citations
  • 2022The orthorhombic-to-monoclinic phase transition in NbCrP – Peierls distortion of the chromium chain2citations
  • 2022Hydrogen induced structural phase transformation in ScNiSn-based intermetallic hydride characterized by experimental and computational studies4citations
  • 2022Hydrogen induced structural phase transformation in ScNiSn-based intermetallic hydride characterized by experimental and computational studies ; ENEngelskEnglishHydrogen induced structural phase transformation in ScNiSn-based intermetallic hydride characterized by experimental and computational studies4citations
  • 2022MAl4Ir2 (M = Ca, Sr, Eu) : superstructures of the KAu4In2 typecitations
  • 2021On the crystal structure and optical spectroscopy of rare earth comprising quaternary tungstates Li3Ba2RE3(WO4)8 (RE = La-Nd, Sm-Ho)8citations
  • 2020Scandium-rich ternary coloring variants of the cubic Ag7+xMg26–x type6citations
  • 2020Squares of gold atoms and linear infinite chains of Cd atoms as building units in the intermetallic phases REAu4Cd2 (RE=La–Nd, Sm) with YbAl4Mo2-type structure4citations
  • 2019Study of the structural transition and hydrogenation of CeTiGe10citations
  • 2019Phase equilibrium in the Gd-Ni-In system at 870 K5citations
  • 2017The nitridoborate nitrides Mg3[BN2]N and Ca3[BN2]N – electronic structure and chemical bonding4citations
  • 2017Electronic structure and chemical bonding in LaIrSi-type intermetallics8citations
  • 2017Hydrogenation-induced cerium valence change in CeNiZn2citations
  • 2016Cerium intermetallics CeTX – review III54citations
  • 2016Hydrogenation studies on NdScSi and NdScGe12citations
  • 2016Cerium intermetallics with TiNiSi-type structure74citations
  • 2016Ternary silicides Sclr4Si2 and RERh4Si2 (RE = Sc, Y, Tb-Lu) and quaternary derivatives RERh4Si2-xSnx (RE = Y, Nd, Sm, Gd-Lu) - structure, chemical bonding and solid state NMR spectroscopy6citations
  • 2015Structure and bonding of Bi4Ir9citations
  • 2015Rhodium-rich germanides RERh4Ge2 (RE = Y, Gd–Lu): structure and bonding6citations
  • 2015LaMgX and CeMgX (X = Ga, In, Tl, Pd, Ag, Pt, Au) with ZrNiAl type structure – A systematic view on electronic structure and chemical bonding3citations
  • 2015Chemical bonding in equiatomic cerium intermetallics – The case of CeMgSn, CePdSn, and CeMgPb3citations
  • 2015Cerium intermetallics with ZrNiAl-type structure -- a review81citations
  • 2015Chemical bonding in RFe6Ge4 (R = Li, Sc, Zr) and LuTi6Sn4 with rhombohedral LiFe6Ge4 type structure7citations
  • 2015Equiatomic cerium intermetallics CeXX' with two p elements21citations
  • 2014The gallium intermetallics REPdGa3 (RE = La, Ce, Pr, Nd, Sm, Eu) with SrPdGa3-type structure30citations
  • 2014Electronic structure, chemical bonding and electrochemical characterization of Li2CuSn2 and Li2AgSn24citations
  • 2014Electronic and magnetic structures and bonding properties of Ce2T2X (T ¼ nd element; X ¼ Mg, Cd, Pb or Sn) intermetallics from first principles9citations
  • 2014La2NiSb - A ternary ordered version of the Bi3Ni type with highly polar bonding3citations
  • 2014Electronic and magnetic structures and bonding properties of Ce2T2X (T = nd element; X = Mg, Cd, Pb or Sn) intermetallics from first principles9citations
  • 2014A metallic room-temperature oxide ion conductor17citations
  • 2014The U4Re7Si6 type - Trends in electronic structure and chemical bonding6citations
  • 2014TbRhSn and DyRhSn - Detailed magnetic and ^{119}Sn Mössbauer spectroscopic studies6citations
  • 2014The family of LiCo6P4 type compounds - trends in electronic structure and chemical bonding5citations
  • 2013Linear infinite cadmium chains in CaAu4Cd2 and other intermetallics with YbMo2Al4-type structure20citations
  • 2013CaTMg2 and CaTCd2 (T = Rh, Pd, Pt) with YPd2Si-type structure6citations
  • 2013An investigation of the electrochemical delithiation process of carbon coated $α-Fe_{2}O_{3}$ nanoparticles23citations
  • 2013Electronic structure and bonding in YTi2Ga4 - A gallide with linear titanium chains and four-bonded gallium atoms10citations
  • 2013ScPdZn and ScPtZn with YalGe type structure - Group-subgroup relation and 45Sc solid state NMR spectroscopy8citations
  • 2012Dimorphic LaPdSn and ErAgSn - A first principles study5citations
  • 2012The role of structure and interface in the performance of TiSnSb as an electrode for Li-ion batteries25citations
  • 2012Underpinning energetics of lithium bonding and stability in the LiePteSn system4citations
  • 2012Segregation of calcium and magnesium into different substructures. Ca4Ag0.948Mg and other compounds with Gd4RhIn-type structure28citations
  • 20127Li and 29Si solid state NMR and chemical bonding of La2Li2Si310citations
  • 2011Influence of the La/M Network on Magnetic Properties of Mn4 Tetrahedra in Intermetallic Compounds La21−δMn8M7C12 (M = Ge, Sn, Sb, Te, Bi)17citations
  • 2011The Solid Solution Lu<sub>2–x</sub>Sc<sub>x</sub>SiO<sub>5</sub>1citations
  • 2011Structure, homogeneity ranges, magnetic, and electrical properties of the ordered Laves phases RE Ni 4 Mg with MgCu 4 Sn type structure35citations
  • 2011Electronic structure and equation of state of PdO 2 from ab initio23citations
  • 2011SrAu 4.76 In 1.24 with YbMo 2 Al 4 -type structure9citations
  • 2011First principles investigations of the hydrogenation effects on the electronic structure and the chemical bonding of CeIrAl5citations
  • 2010New high temperature modification of CeTiGe : structural characterization and physical properties14citations
  • 2010Condensed [OPr<sub>4</sub>]<sup>10+</sup> and Discrete [AsO<sub>3</sub>]<sup>3–Ψ1</sup>-Tetrahedra in Pr<sub>5</sub>O<sub>4</sub>Cl[AsO<sub>3</sub>]<sub>2</sub>15citations
  • 2010Intermetallic Magnesium Compounds RE<sub>2</sub>Ni<sub>2</sub>Mg<sub>3</sub> (RE =Gd, Dy–Tm, Lu) with Tb<sub>2</sub>Ni<sub>2</sub>Mg<sub>3</sub>-type Structure4citations
  • 2010^{155}Gd Mössbauer spectroscopy on intermetallics : an overview13citations
  • 2010Hydrogenation behavior of the solid solutions RE 4 NiMg 1− x Al x and RE 4− y NiMg 1+ y with RE = Gd and Y12citations
  • 2010Ternary Silicides Sc 3 T Si 3 ( T = Ru, Rh, Ir, Pt) – Structure, Chemical Bonding, and Solid State NMR15citations
  • 2010La 6 Pd 13 Cd 4 and Ce 6 Pd 13 Cd 4 with palladium-centred rare earth octahedra: synthesis, structure, and chemical bonding4citations
  • 2009Rare earth metal rich magnesium compounds RE 4 NiMg ( RE =Y, Pr–Nd, Sm, Gd–Tm, Lu)—Synthesis, structure, and hydrogenation behavior38citations
  • 2009The layered iron arsenide oxides Sr2CrO3FeAs and Ba2ScO3FeAs35citations
  • 2009Unusually short Ce-Ru distances in CeRuAl and related compounds47citations
  • 2009The polar mixed-valent lanthanum iron(II, III) sulfide La3Fe2-δS75citations
  • 2009Metamagnetic transition in the 75 K antiferromagnet Gd 4 Co 2 Mg 310citations
  • 2008Structure and properties of RERhZn (RE = La, Ce, Pr, Nd)19citations
  • 2008Rare Earth-rich magnesium compounds RE4PdMg (RE = Y, Sm, Gd) and RE4PtMg (RE = Y, Nd, Sm, Gd)13citations
  • 2008Rare earth metal-rich magnesium compounds RE4IrMg (RE = Y, La, Pr, Nd, Sm, Gd, Tb, Dy) and RE23Ir7Mg4 (RE = La, Ce, Pr, Nd)37citations
  • 2007Hydrogenation of the Kondo compound CePtIn7citations
  • 2007Structure refinement of CePtSi and hydrogenation behavior of CePdGe, CePtS and CePtGe8citations
  • 2007New intermetallic compounds RE4Co2Mg3 (RE = Pr, Gd, Tb, Dy) - Syntheses, structure, and chemical bonding13citations
  • 2007Cobalt centered trigonal RE6 prisms and Mg4 clusters as basic structural units in RE4CoMg (RE = Y, La, Pr, Nd, Sm, Gd-Tm)38citations
  • 2007Rare Earth-rich Magnesium Compounds RE4RhMg (1{RE} = Y, La - Nd, Sm, Gd - Tm, Lu)22citations
  • 2007Chemical bonding in EuTGe (T=Ni, Pd, Pt) and physical properties of EuPdGe12citations
  • 2006New intermetallic compounds Nd4Co2Mg3 and Sm4Co2Mg3 and Sm4Co2Mg3 - an intergrowth of AlB2 and CsCl related slabs17citations

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Co-Authors (by relevance)

  • Ponniah, Vajeeston
  • Denys, Roman Volodymyrovich
  • Berezovets, Vasyl
  • Dankelman, Robert
  • Block, Theresa
  • Fischer Eggert, Bruno Guilherme
  • Akselrud, Lev G.
  • Yartys, Volodymyr
  • Wragg, David Stephen
  • Plomp, Jeroen
  • Plomp, J.
  • Dankelman, B. J. R.
  • Vajeeston, Ponniah
  • Wragg, David
  • Yartys, Volodymyr A.
  • Denys, Roman V.
  • Reimann, Maximilian K.
  • Janka, Oliver
  • Gießelmann, Elias C. J.
  • Engel, Stefan
  • Kösters, Jutta
  • Pröbsting, Wilma
  • Harmening, Thomas
  • Eckert, Hellmut
  • Seidel, Stefan
  • Fehse, Constanze
  • Klenner, Steffen
  • Matar, Samir F.
  • Wittmann, Sarah
  • Murshed, Mohammad Mangir
  • Gesing, Thorsten M.
  • Schumacher, Lars
  • Koldemir, Aylin
  • Hlukhyy, Viktor
  • Zaremba, Nazar
  • Pavlyuk, Volodymyr
  • Stegemann, Frank
  • Reimann, Maximilian Kai
  • Gießelmann, Elias Carl Johannes
  • Kuwata, Yoshiki
  • Kotegawa, Hisashi
  • Paulsen, Christian Jens Gert
  • Harima, Hisatomo
  • Tou, Hideki
  • Sugawara, Hitoshi
  • Chernyshov, Dmitry
  • Havela, Ladislav
  • Antonov, Vladimir
  • Fedotov, Vladimir
  • Heere, Michael
  • Berezovets, Vasyl V.
  • Senyshyn, Anatoliy
  • Keil, Jan-Niklas
  • Rosner, Florian
  • Jüstel, Thomas
  • Paulsen, Christian
  • Gulay, Nataliya L.
  • Kalychak, Yaroslav M.
  • Oeckler, Oliver
  • Bönnighausen, Judith
  • Benndorf, Christopher
  • Gaudin, Etienne
  • Mahon, Tadhg
  • Chevalier, Bernard
  • Tencé, Sophie
  • Kalychak, Yaroslav
  • Dzevenko, Mariya
  • Zaremba, Vasyl
  • Al Alam, Adel F.
  • Nakhl, Michel
  • Heying, Birgit
  • Bobet, Jean-Louis
  • Mahon, Tadgh
  • Flacau, Roxana
  • Rodewald, Ute Ch.
  • Niehaus, Oliver
  • Voßwinkel, Daniel
  • Rodewald, Ute Ch
  • Isaeva, Anna
  • Schäfer, Konrad
  • Ruck, Michael
  • Etourneau, Jean
  • Fickenscher, Thomas
  • Ouaini, Naïm
  • Gerke, Birgit
  • Balducci, Andrea
  • Schirmer, Niel
  • Winter, Florian
  • Schwickert, Christian
  • Janek, Jürgen
  • Baranov, Alexey I.
  • Eufinger, Jens Peter
  • Rasche, Bertold
  • Heise, Martin
  • Gurgul, Jacek
  • Łątka, Kazimierz
  • Pacyna, Andrzej W.
  • Peter, Sebastian C.
  • Tappe, Frank
  • Michael, Johnscher
  • Kersting, Marcel
  • Berkemeier, Frank
  • Klamor, Sebastian
  • Rana, Jatinkumar
  • Brandt, Adrian
  • Mishra, Trinath
  • Deters, Heinz
  • Hoffmann, Rolf-Dieter
  • Huppertz, Hubert
  • Sougrati, Moulay Tahar
  • Grey, Clare P.
  • Marino, Cyril
  • Ménétrier, Michel
  • Gerke, B.
  • Monconduit, Laure
  • Huo, Hua
  • Dupke, Sven
  • Winter, Martin
  • Langer, Thorsten
  • Benbow, Evan M.
  • Latturner, Susan E.
  • Schellenberg, Inga
  • Balamurugan, Sarkarainadar
  • Yahia, Hamdi Ben
  • Decourt, Rodolphe
  • Linsinger, Stefan
  • Eul, Matthias
  • Demazeau, Gérard
  • Möller, Manfred H.
  • Muts, Ihor
  • Zaremba, Vasyl I.
  • Ouaïni, Naïm
  • Hermes, Wilfried
  • Schleid, Thomas
  • Villesuzanne, Antoine
  • Couillaud, Samuel
  • Duée, Cédric
  • Rougier, Aline
  • Eckert, Helmut
  • Mohr, Daniel
  • Roquefere, Jean-Gabriel
  • Petrache Stan, Cristina Iuliana
  • Tuncel, Selcan
  • Hummel, Franziska
  • Tegel, Marcus
  • Johrendt, Dirk
  • Lackner, Sebastian
  • Bräunling, Daniel
  • Schnelle, Walter
  • Sebastian, C. Peter
  • Rosner, Helge
  • Mills, Allison M.
  • Gorsse, Stéphane
  • Rocquefelte, Xavier
  • Müllmann, Ralf
  • Gautier, Régis
  • Rosenhahn, Carsten
  • Kotzybac, Gunter
  • Mosel, Bernd D.
  • Halet, Jean-François
OrganizationsLocationPeople

article

Trivalent europium – a scarce case in intermetallics

  • Gießelmann, Elias Carl Johannes
  • Janka, Oliver
  • Pöttgen, Rainer
  • Engel, Stefan
Abstract

<jats:title>Abstract</jats:title><jats:p>In most intermetallic europium compounds, the Eu atoms exhibit a divalent oxidation state with a high effective magnetic moment since Eu<jats:sup>2+</jats:sup> is isoelectronic with Gd<jats:sup>3+</jats:sup>. Trivalent intermetallic Eu compounds, in contrast, are extremely scarce and under 20 examples are known to literature. This mini-review summarizes the known binary and ternary examples along with their crystal-chemical peculiarities as well as their magnetic and <jats:sup>151</jats:sup>Eu Mössbauer spectroscopic behavior. Additionally, compounds that exhibit valence phase transitions are summarized.</jats:p>

Topics
  • impedance spectroscopy
  • compound
  • phase
  • phase transition
  • intermetallic
  • Europium