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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Gießelmann, Elias Carl Johannes
Saarland University
in Cooperation with on an Cooperation-Score of 37%
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article
Trivalent europium – a scarce case in intermetallics
Abstract
<jats:title>Abstract</jats:title><jats:p>In most intermetallic europium compounds, the Eu atoms exhibit a divalent oxidation state with a high effective magnetic moment since Eu<jats:sup>2+</jats:sup> is isoelectronic with Gd<jats:sup>3+</jats:sup>. Trivalent intermetallic Eu compounds, in contrast, are extremely scarce and under 20 examples are known to literature. This mini-review summarizes the known binary and ternary examples along with their crystal-chemical peculiarities as well as their magnetic and <jats:sup>151</jats:sup>Eu Mössbauer spectroscopic behavior. Additionally, compounds that exhibit valence phase transitions are summarized.</jats:p>