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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Katančić, Zvonimir
European Commission
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Pristine and UV-Weathered PET Microplastics as Water Contaminants: Appraising the Potential of the Fenton Process for Effective Remediationcitations
- 2024Inkjet printed acrylate-urethane modified poly(3,4-ethylenedioxythiophene) flexible conductive films
- 2022Intrinsically Stretchable Poly(3,4-ethylenedioxythiophene) Conducting Polymer Film for Flexible Electronicscitations
- 2021Solar Light Activation of Persulfate by TiO<sub>2</sub>/Fe<sub>2</sub>O<sub>3</sub> Layered Composite Films for Degradation of Amoxicillin: Degradation Mechanism, Matrix Effects, and Toxicity Assessmentscitations
- 2021Solar Light Activation of Persulfate by TiO2 / Fe2O3 Layered Composite Films for Degradation of Amoxicillin: Degradation Mechanism, Matrix Effects, and Toxicity Assessmentscitations
- 2021Development of PE/PCL Bilayer Films Modified with Casein and Aluminum Oxidecitations
- 2019Efficiency of TiO2 catalyst supported by modified waste fly ash during photodegradation of RR45 dyecitations
- 2018Fly ash supported photocatalytic nanocomposite poly(3,4‐ethylenedioxythiophene)/TiO<sub>2</sub> for azo dye removal under simulated solar irradiationcitations
- 2014Thermal decomposition of fire-retarded high-impact polystyrene and high-impact polystyrene/ethylene–vinyl acetate blend nanocomposites followed by thermal analysiscitations
- 2014Effect of modified nanofillers on fire retarded high-density polyethylene/wood compositescitations
- 2012Influence of calcium carbonate filler and mixing type process on structure and properties of styrene–acrylonitrile/ethylene–propylene–diene polymer blendscitations
- 2011Effect of preparation on morphology-properties relationships in SAN/EPDM/PCC compositescitations
Places of action
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article
Inkjet printed acrylate-urethane modified poly(3,4-ethylenedioxythiophene) flexible conductive films
Abstract
Flexible electronics is a new generation of electronic devices in which electronic components are integrated into flexible substrates. It is used in the fabrication of displays, solar cells, integrated circuits, and increasingly in the fabrication of electronic skin (E-skin), which can mimic the properties of human skin by being able to follow skin movements and flexures without loss of mechanical and electrical properties. E-skin is suitable for integrating various sensors to monitor personal health. Conductive polymers are used in flexible electronics due to their electrical conductivity, low mass, and stability. However, their main disadvantage is their brittleness, which is why they don’t possess flexibility property without modification. Therefore, in this work, the conductive polymer poly(3,4-ethylenedioxythiophene) (PEDOT) was used as the main chain and the side branches of poly(acrylate-urethane) (PAU) were grafted onto it by atom transfer radical polymerization (ATRP) onto it, obtaining the grafted copolymer PEDOT-g-PAU. In this way, the main chain of PEDOT retains the property of electrical conductivity without losing conjugation, while the side branches of PAU have the ability to crosslink non-covalently through hydrogen bonds with PAU side branches of adjacent polymer molecules due to the presence of oxygen in their structure. The presence of hydrogen bonds allows increasing the stretchability and flexibility of the material, and they also have the ability to spontaneously renew themselves when they break due to excessive stress. Three different synthesis conditions were used to obtain polymers of different structure, which were characterized by Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance (NMR), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and measurement of electrical conductivity with a four-point probe (4PP) method. The obtained graft copolymer was prepared in the form of ink and printed on a polyurethane (PU) substrate using inkjet technique. The conductivity of the printed layer, its elongation and adhesion were investigated, while possible delamination of the printed polymer layer was also monitored. The results showed that the PEDOT-g-PAU copolymer was successfully synthesized and inkjet printing on PU film was successful. The obtained material has satisfactory electrical and mechanical properties and could be used for the integration of fully functional biosensors with further optimization of the composition.