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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Fischer, Horst
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2022First measurement of the surface tension of a liquid scintillator based on Linear Alkylbenzene (HYBLENE 113)
- 2019Shipborne measurements of total OH reactivity around the Arabian Peninsula and its role in ozone chemistrycitations
- 2019Development of a solvent-free polylactide/calcium carbonate composite for selective laser sintering of bone tissue engineering scaffoldscitations
- 2016Structuring of bioactive glass surfaces at the micrometer scale by direct casting intended to influence cell responsecitations
- 2016Calcium phosphate/microgel composites for 3D powderbed printing of ceramic materialscitations
- 2015Bioactive and Thermally Compatible Glass Coating on Zirconia Dental Implantscitations
- 2015Low-aspect ratio nanopatterns on bioinert alumina influence the response and morphology of osteoblast-like cellscitations
- 2011Synthesis of novel tricalcium phosphate-bioactive glass composite and functionalization with rhBMP-2.citations
- 2008Chemical strengthening of a dental lithium disilicate glass-ceramic materialcitations
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article
Calcium phosphate/microgel composites for 3D powderbed printing of ceramic materials
Abstract
<jats:title>Abstract</jats:title> <jats:p>Composites of microgels and calcium phosphates are promising as drug delivery systems and basic components for bone substitute implants. In this study, we synthesized novel composite materials consisting of pure <jats:italic>β</jats:italic>-tricalcium phosphate and stimuli-responsive poly(<jats:italic>N</jats:italic>-vinylcaprolactam-co-acetoacetoxyethyl methacrylate-co-vinylimidazole) microgels. The chemical composition, thermal properties and morphology for obtained composites were extensively characterized by Fourier transform infrared, X-ray photoelectron spectroscopy, IGAsorp moisture sorption analyzer, thermogravimetric analysis, granulometric analysis, ESEM, energy dispersive X-ray spectroscopy and TEM. Mechanical properties of the composites were evaluated by ball-on-three-balls test to determine the biaxial strength. Furthermore, initial 3D powderbed-based printing tests were conducted with spray-dried composites and diluted 2-propanol as a binder to evaluate a new binding concept for <jats:italic>β</jats:italic>-tricalcium phosphate-based granulates. The printed ceramic bodies were characterized before and after a sintering step by ESEM. The hypothesis that the microgels act as polymer adhesive agents by efficient chemical interactions with the <jats:italic>β</jats:italic>-tricalcium phosphate particles was confirmed. The obtained composites can be used for the development of new scaffolds.</jats:p>