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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Wolverson, Daniel
University of Bath
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2024Porous Structure Enhances the Longitudinal Piezoelectric Coefficient and Electromechanical Coupling Coefficient of Lead-Free (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3citations
- 2024Spin-order-dependent magneto-elastic interactions in two dimensional antiferromagnetic MnPSe3 observed through Raman spectroscopycitations
- 2024Porous structure enhances the longitudinal piezoelectric coefficient and electromechanical coupling coefficient of lead‐free (Ba 0.85 Ca 0.15 )(Zr 0.1 Ti 0.9 )O 3citations
- 2023Exploring the Charge Density Wave Phase of 1T-TaSe2citations
- 2020Excitonic and lattice contributions to the charge density wave in 1T-TiSe2 revealed by a phonon bottleneckcitations
- 2020Phase behavior and substitution limit of mixed cesium-formamidinium lead triiodide perovskitescitations
- 2018Investigating nanostructures in carbon fibres using Raman spectroscopycitations
- 2017Strain-induced phonon shifts in tungsten disulfide nanoplatelets and nanotubescitations
- 2017Interfacial control in graphene- and transition metal dichalcogenide-polymer nanocomposites
- 2017Electronic band structure of ReS 2 by high-resolution angle-resolved photoemission spectroscopycitations
- 2017Electronic bandstructure and van der Waals coupling of ReSe2 revealed by high-resolution angle-resolved photoemission spectroscopycitations
- 2017Electronic band structure of ReS2 by high-resolution angle-resolved photoemission spectroscopycitations
- 2016Strain-induced phonon shifts in tungsten disulfide nanoplatelets and nanotubescitations
- 2016A comparison of the micromechanics of graphene- and transition metal dichalcogenide-nanocomposites
- 2014Raman spectra of monolayer, few-layer, and bulk ReSe 2 :An anisotropic layered semiconductorcitations
- 2014Raman spectra of monolayer, few-layer, and bulk ReSe2citations
- 2013Investigation of the sp3 structure of carbon fibres uUsing Uv-Raman spectroscopycitations
- 2012Porous silicon nanocrystals in a silica aerogel matrixcitations
- 2010Excitons in motion in II-VI semiconductorscitations
- 2010Carbon nanoparticle surface functionalisation: converting negatively charged sulfonate to positively charged sulfonamidecitations
- 2008Coherent Raman detected electron spin resonance spectroscopy of metalloproteins: linking electron spin resonance and magnetic circular dichroismcitations
- 2008Thin-film modified electrodes with reconstituted cellulose-PDDAC films for the accumulation and detection of triclosancitations
- 2000Band structure parameters of quaternary phosphide semiconductor alloys investigated by magneto-optical spectroscopy
Places of action
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article
Phase behavior and substitution limit of mixed cesium-formamidinium lead triiodide perovskites
Abstract
The mixed cation lead iodide perovskite photovoltaics show improved stability following site substitution of cesium ions (Cs+) onto the formamidinium cation sites (FA+) of (CH(NH2)2PbI3 (FAPbI3) and increased resistance to formation of the undesirable ∂-phase. The structural phase behavior of Cs0.1FA0.9PbI3 has been investigated by neutron powder diffraction (NPD), complemented by single crystal and power X-ray diffraction and photoluminescence spectroscopy. The Cs-substitution limit has been determined to be less than 15%, and the cubic α-phase, Cs0.1FA0.9PbI3, is shown to be synthesizable in bulk and stable at 300 K. On cooling the cubic Cs0.1FA0.9PbI3, a slow, second-order cubic to tetragonal transition is observed close to 290 K, with variable temperature NPD indicating the presence of the tetragonal β-phase, adopting the space group P4/mbm between 290 and 180 K. An orthorhombic phase or twinned tetragonal phase is formed below 180 K, and the temperature for further transition to a disordered state is lowered to 125 K compared to that seen in phase pure α-FAPbI3 (140 K). These results demonstrate the importance of understanding the effect of cation site substitution on structure–property relationships in perovskite materials.