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| Naji, M. |
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| Motta, Antonella |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Ali, M. A. |
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| Rančić, M. |
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| Azevedo, Nuno Monteiro |
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Pichler, Birgit Elvira
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (5/5 displayed)
- 2019Ethanol: Tolerant Oxygen Reduction Reaction Catalysts in Alkaline Mediacitations
- 2018The impact of operating conditions on component and electrode development for zinc-air flow batteriescitations
- 2017Bifunctional electrode performance for zinc-air flow cells with pulse chargingcitations
- 2017Ethanol - Tolerant Pt-free Cathode Catalysts for the Alkaline Direct Ethanol Fuel Cellcitations
- 2017Ethanol tolerant precious metal free cathode catalyst for alkaline direct ethanol fuel cellscitations
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article
Ethanol - Tolerant Pt-free Cathode Catalysts for the Alkaline Direct Ethanol Fuel Cell
Abstract
The structure and electrochemical activity of carbon supported Pt-free cathode catalysts (Ag/C, Mn3O4/C and AgMnO2/C) are investigated by means of transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD) and cyclic voltammetry (CV). The catalysts display ethanol-tolerance for the oxygen reduction reaction (ORR) in 0.1 M KOH electrolyte containing ethanol at different temperatures. Because crossover of ethanol from anode to cathode through the membrane can occur in alkaline direct ethanol fuel cells (ADEFCs), selectivity of the cathode catalyst is of high importance. AgMnO2/C catalyst exhibits the highest catalytic activity toward ORR in presence of alkaline electrolytes containing ethanol.