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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Ali, M. A. |
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Azevedo, Nuno Monteiro |
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article
Transparent Ce<sup>3+</sup>-doped fluorapatite (FAP) ceramics fabricated by spark plasma sintering (SPS)
Abstract
<jats:p>Polycrystalline Ce<jats:sup>3+</jats:sup>-doped fluorapatite (Ce:FAP) transparent ceramics with fine microstructures were fabricated through liquid-phase synthesis for the initial powder and spark plasma sintering (SPS) for full densification. These ceramics were confirmed to have a single-phase crystal structure, and the average grain sizes were determined to be 139 and 135 nm for the 1 and 2 at.% Ce-doping concentrations, respectively. Their emission spectra revealed that the fabricated ceramics convert UV light to visible light emission due to the 5<jats:italic>d</jats:italic>→4<jats:italic>f</jats:italic> electronic transition of Ce<jats:sup>3+</jats:sup>. These ceramics are expected to be useful in photonic applications.</jats:p>