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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bakandritsos, Aristides
Technical University of Ostrava
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2024Unveiling the potential of covalent organic frameworks for energy storage: Developments, challenges, and future prospectscitations
- 2022Microwave Synthesis, Characterization and Perspectives of Wood Pencil-Derived Carboncitations
- 2022Probing the effect of a glass network on the synthesis and luminescence properties of composite perovskite glasses [Invited]citations
- 2021Covalent Graphene-MOF Hybrids for High-Performance Asymmetric Supercapacitorscitations
- 2021The Hallmarks of Copper Single Atom Catalysts in Direct Alcohol Fuel Cells and Electrochemical CO<sub>2</sub> Fixationcitations
- 2021Single Co‐Atoms as Electrocatalysts for Efficient Hydrazine Oxidation Reactioncitations
- 2021The Hallmarks of Copper Single Atom Catalysts in Direct Alcohol Fuel Cells and Electrochemical CO2 Fixationcitations
- 2020Multi-Leg TiO2 Nanotube Photoelectrodes Modified by Platinized Cyanographene with Enhanced Photoelectrochemical Performancecitations
- 2012Merging high doxorubicin loading with pronounced magnetic response and bio-repellent properties in hybrid drug nanocarrierscitations
Places of action
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article
Probing the effect of a glass network on the synthesis and luminescence properties of composite perovskite glasses [Invited]
Abstract
<jats:p>All-inorganic cesium lead bromide perovskite nanocrystals (PNCs) are highly promising candidates for various optoelectronic and photonic devices. However, poor stability upon exposure to moisture and lead toxicity issues significantly limit their applications. A modern and promising strategy on resolving these issues is the encapsulation of highly luminescent (PNCs) within transparent inorganic oxide glasses. While the encapsulation procedure effect on the development and properties of the so-formed PV-Glasses has been explored in detail, there is lack of understanding the influence of the selected glass composition and network type on the outcome of the synthesis. Herein we report on the synthesis and photoluminescence properties of composite perovskite-glasses upon growing all-inorganic lead halide perovskites within three different types of inorganic oxide glasses. When a silver metaphosphate glass matrix is used it is revealed that the low glass transition temperature of the phosphate glass limits significantly the temperature range of the required post-melting annealing treatment, while the lead salt precursors react with the phosphate entities of the network destroying the stoichiometry of the PNCs. As a result the formation of PNCs is hindered. As a consequence, a double network former borophosphate glass was employed as a suitable host. While annealing treatments at higher temperature were facilitated in this case, it is found that the high silver content becomes an obstacle for the perovskite formation. In view of these findings, cesium lead bromide (CsPbBr<jats:sub>3</jats:sub>) and cesium lead iodide (CsPbI<jats:sub>3</jats:sub>) composite perovskite borate glasses were synthesized and found to be suitable hosts. Indeed, such composite glasses exhibit interesting photoluminescence properties that are compared with those of PNCs outside the glass matrix.</jats:p>