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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Pietrzak, Tomasz
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2021Towards deeper understanding of multifaceted chemistry of magnesium alkylperoxidescitations
- 2019Multifold pressure-induced increase of electric conductivity in LiFe<inf>0.75</inf>V<inf>0.10</inf>PO<inf>4</inf> glasscitations
- 2016Dependence of a glass transition temperature on a heating rate in DTA experiments for glasses containing transition metal oxidescitations
- 2016Synthesis of nanostructured Li3Me2(PO4)2F3 glass-ceramics (Me = V, Fe, Ti)citations
- 2016Nanocrystallisation in vanadate phosphate and lithium iron vanadate phosphate glassescitations
- 2015High electronic conductivity in nanostructured materials based on lithium-iron-vanadate-phosphate glassescitations
- 2013Isothermal nanocrystallization of vanadate-phosphate glassescitations
- 2013Novel vanadium-doped olivine-like nanomaterials with high electronic conductivitycitations
- 2011Electrical properties and thermal stability of FePO4 glasses and nanomaterialscitations
- 2011Electrical properties vs. microstructure of nanocrystallized V2O5–P2O5 glasses — An extended temperature range studycitations
- 2009Correlation between electrical properties and microstructure of nanocrystallized V2O5–P2O5 glassescitations
Places of action
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article
Nanocrystallisation in vanadate phosphate and lithium iron vanadate phosphate glasses
Abstract
In this paper we have summarised our recent research on nanocrystallisation in vanadate-phosphate (VP) and lithiumiron-vanadate-phosphate (LFVP) glasses. These materials are amorphous analogues of crystalline V2O5 or LiFePO4 cathode materials for Li-ion batteries. The influence of synthesis and further thermal treatment conditions on electrical, thermal and electrochemical properties has been studied. In particular, a significant increase in electronic conductivity (up to 0.7×10-1 and 7×10-3 S/cm for VP and LFVP nanomaterials, respectively) was observed as a result of thermal nanocrystallisation. The microstructure has been observed and studied by a combination of XRD, SEM/TEM and EDX methods. Densely packed, small (15-30 nm and 5-15 nm in size) grains were observed in VP and LFVP materials, respectively. The significant increase in the conductivity is discussed in terms of Mott's model of electron hopping and a core-shell model. copyright © of the Society.