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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Ali, M. A. |
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Rančić, M. |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Kansy, J.
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article
A study of point defects in the B2-phase region of the Fe-Al system by mössbauer spectroscopy
Abstract
<p>In this work, we employed the Mossbauer spectroscopy and X-ray powder diffraction in a study of point defect formation in intermetallic phases of the B2 structure of the Fe-Al system as a function of Al concentration. The results are compared with the concentrations of point defect determined from positron annihilation data. In the Mössbauer effect, two types of samples are investigated: Fe-Al alloys with few additives obtained by induction melting and Al-rich metallic powders produced by the self-decomposition method and intensive grinding of high energy in the electro-magneto-mechanical mill. We present the values of the<sup>57</sup>Fe isomer shift and quadrupole splitting for the components describing the point defect in the local environment of a Mossbauer nuclide. The concentration of the Fe vacancies and Fe atoms substituting Al (Fe-AS) are determined. The results showed that an increase in Al content causes an increase in vacancy and Fe-AS concentration.</p>