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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Stampanoni, M.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2016Self-assembly nanostructured gold for high aspect ratio silicon microstructures by metal assisted chemical etchingcitations
- 2015Dynamic Operation of HT-PEFC: in-operando imaging of phosphoric acid profiles and (re)distributioncitations
- 2012Pitting corrosion of stainless steel
- 2011Pinch-off of rods by bulk diffusioncitations
- 2011Progress in in situ X-ray tomographic microscopy of liquid water in gas diffusion layers of PEFCcitations
- 2011Pitting corrosion of stainless steel: measuring and modelling pit propagation in support of damage prediction for radioactive waste containerscitations
- 2010Connectivity of phases and growth mechanisms in peritectic alloys solidified at low speed: an X-ray tomography study of Cu-Sn
- 2007Synchrotron X-ray microtomography study of the role of Y in corrosion of magnesium alloy WE43citations
Places of action
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article
Pitting corrosion of stainless steel: measuring and modelling pit propagation in support of damage prediction for radioactive waste containers
Abstract
In situ synchrotron radiography has been used to observe the evolution of two-dimensional pits growing in stainless steel foils under electrochemical control in chloride solutions. A method for extracting the key kinetic parameters from radiographs is under development to provide data for validating and calibrating a two-dimensional finite element model previously developed by Laycock and White. The local current density along the boundary of a pit is directly measured from the radiographs. Then, the local metal ion concentration and potential drop inside the pit cavity are backcalculated using transport equations and the requirement to maintain charge neutrality, giving the relationship between current density, solution composition and interfacial potential. Preliminary comparisons show qualitative correlation between the model and extracted data; quantitative comparison is under way.