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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Evans, Andrew
in Cooperation with on an Cooperation-Score of 37%
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Publications (7/7 displayed)
- 2023Investigating the Molecular Orientation and Thermal Stability of Spiro‐OMeTAD and its Dopants by Near Edge X‐Ray Absorption Fine Structurecitations
- 2023Characteristics of the sore throat test and treat service in community pharmacies (STREP) in Wales: cross-sectional analysis of 11 304 consultations using anonymized electronic pharmacy recordscitations
- 2022Identifying chemical and physical changes in wide-gap semiconductors using real-time and near ambient-pressure XPScitations
- 2014Characterization of spray-coating methods for conjugated polymer blend thin filmscitations
- 2013Transport and optical gaps and energy band alignment at organic-inorganic interfacescitations
- 2012Iron-mediated growth of epitaxial graphene on SiC and diamondcitations
- 2004Interfacial structure of annealed alumina-zirconia-silicate nanoceramicscitations
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article
Interfacial structure of annealed alumina-zirconia-silicate nanoceramics
Abstract
<p>An alumina-zirconia nanocomposite has been produced using the chloride sol-gel method and embedded into a silicate matrix by dispersing the nanocomposite into a powdered silica glass and subsequent annealing. The resultant nanoceramic was subjected to <sup>27</sup>Al magic angle spinning (MAS) NMR, small angle X-ray scattering (SAXS), and X-ray photoelectron spectroscopy (XPS), leading to a core-shell type model of the interfacial region. Initially the particles are agglomerated with the shell containing mainly atoms of octahedral coordination and the core aluminium atoms of tetrahedral coordination. Upon annealing the agglomerates break up, causing a change in the coordination of the aluminium atoms. As the atoms diffuse into the matrix, the ones that were initially in the shell change to be tetrahedrally coordinated, and therefore increase the overall population of tetrahedrally coordinated aluminium atoms within the interface.</p>