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Yahya, Mza
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article
Highly conducting corn starch doped ionic liquid solid polymer electrolyte for energy storage devices
Abstract
<jats:p> In this study, a new biopolymer electrolyte (BPE) is successfully developed using corn starch complexed with ammonium iodide (NH<jats:sub>4</jats:sub>I) as host, and low viscosity ionic liquid 1-Ethyl, 3-Methyl Imidazolium Thiocyanate (EMImSCN), as a plasticizer. This ionic liquid doped BPE shows high ionic conductivity of the order 10<jats:sup>−4</jats:sup> S/cm and electrochemical stability window more than 3 V, which is suitable for electrochemical application. The ionic transference number (t<jats:sub>ion</jats:sub>) of 0.98 confirms the system to be predominantly ionic in nature. Fourier transform infrared spectroscopy (FTIR) shows complex nature, while polarized optical microscopy (POM) gives us an idea about the semi-crystalline nature of BPE. Maximum conducting ionic liquid doped BPE sandwiched electric double layer capacitor (EDLC) and dye sensitize solar cell (DSSC) shows efficient performance. </jats:p>