| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Podda, Enrico
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (5/5 displayed)
- 2021Morpholine- and Thiomorpholine-Based Amidodithiophosphonato Nickel Complexes: Synthesis, Characterization, P-N Cleavage, Antibacterial Activity and Silica Nano-Dispersion.citations
- 2021Morpholine- and Thiomorpholine-Based Amidodithiophosphonato Nickel Complexes: Synthesis, Characterization, P-N Cleavage, Antibacterial Activity and Silica Nano-Dispersioncitations
- 2021Morpholine- and Thiomorpholine-based amidodithiophosphonato nickel complexes: synthesis, characterization, P–N cleavage, antibacterial activity and silica nano-dispersioncitations
- 2017Mechanosynthesis of coordination polymers based on dithiophosphato and dithiophosphonato NiII complexes and 1,4-di(3-pyridinyl)buta-1,3-diyne ligandcitations
- 2017Mechanosynthesis of coordination polymers based on dithiophosphato and dithiophosphonato NiIIcomplexes and 1,4-di(3-pyridinyl)buta-1,3-diyne ligandcitations
Places of action
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article
Morpholine- and Thiomorpholine-Based Amidodithiophosphonato Nickel Complexes: Synthesis, Characterization, P-N Cleavage, Antibacterial Activity and Silica Nano-Dispersion.
Abstract
The reactivity of thiomorpholinium <i>P</i>-(4-methoxyphenyl)-<i>N</i>-thiomorpholin-amidodithiophosphonate (<b>S-MorH<sup>+</sup>₂)(S-Mor-adtp<sup>-</sup>)</b> and morpholinium <i>P</i>-(4-methoxyphenyl)-<i>N</i>-morpholin-amidodithiophosphonate <b>(O-MorH<sup>+</sup>₂)(O-Mor-adtp<sup>-</sup>)</b> towards nickel (II) dichloride hexahydrated is presented and the hydrolysis of the relevant metal complexes investigated. The hydrolytic products (S-MorH<sup>+</sup>₂)₂ [Ni(dtp)₂]²- and (O-MorH<sup>+</sup>₂)₂[Ni(dtp)₂]²- were characterized by means of FT-IR, <sup>1</sup>H, and <sup>31</sup>P NMR and XRD and the experimented P-N cleavage investigated and elucidated by means of DFT calculations. The antimicrobial activity of the neutral nickel complex <b>[Ni(S-Mor-adtp)₂]</b> was tested against a set of Gram-positive and Gram-negative bacteria alongside with its nanodispersion in a silica matrix. The complex [Ni(S-Mor-adtp)₂] did not show antibacterial activity, whilst the nano-dispersed sample <b>[Ni(S-Mor-adtp)₂]_SiO₂</b> demonstrated inhibition to growth of <i>Staphylococcus aureus</i>. The nanocomposites were fully characterized by means of XRPD, TGA, SEM and dinitrogen sorption techniques.