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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bellucci, Stefano
University of Cassino and Southern Lazio
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2024Sono-synthesis and characterization of next-generation antimicrobial ZnO/TiO2 and Fe3O4/TiO2 bi-nanocomposites, for antibacterial and antifungal applicationscitations
- 2024Studies of Fractal Microstructure in Nanocarbon Polymer Composites
- 2023Tunable optical and semiconducting properties of eco-friendly-prepared reduced graphene oxide
- 2022Synthesis and characterization of MWCNT-COOH/Fe3O4 and CNT-COOH/Fe3O4/NiO nanocomposites: assessment of adsorption and photocatalytic performancecitations
- 2022Study of Barium Adsorption from Aqueous Solutions Using Copper Ferrite and Copper Ferrite/rGO Magnetic Adsorbentscitations
- 2021Oxidized alginate dopamine conjugate: In vitro characterization for nose-to-brain delivery applicationcitations
- 2019Novel non-destructive evaluation technique for the detection of poor dispersion of carbon nanotubes in nanocompositescitations
- 2018Electrical Permittivity and Conductivity of a Graphene Nanoplatelet Contact in the Microwave Rangecitations
- 2016Regulation of angiogenesis through the efficient delivery of microRNAs into endothelial cells using polyamine-coated carbon nanotubescitations
- 2014Dielectric properties of graphite-based epoxy compositescitations
Places of action
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article
Study of Barium Adsorption from Aqueous Solutions Using Copper Ferrite and Copper Ferrite/rGO Magnetic Adsorbents
Abstract
<jats:p>The development of advanced materials for the removal of heavy metal ions is a never-ending quest of environmental remediation. In this study, a facile and cost-effective approach was employed to synthesize copper ferrite (CF) and copper ferrite/reduced graphene oxide (CG) by microwave assisted combustion method for potential removal of barium ions from aqueous medium. The physiochemical characterizations indicated the formation of magnetic nanocomposite with an average crystallite size of CF and CG is 32.4 and 30.3 nm and with specific surface area of 0.66 and 5.74 m2/g. The magnetic results possess multidomain microstructures with saturation magnetization of 37.11 and 33.84 emu/g for CF and CG. The adsorption studies prove that upon addition of rGO on the spherical spinel ferrite, the adsorption performance was greatly improved for CG nanocomposite when compared with the bare CF nanoparticles. The proposed magnetic adsorbent demonstrated a relatively high Ba2+ adsorption capacity of 161.6 mg·g-1 for CG nanocomposite when compared to 86.6 mg·g-1 for CF nanoparticles under optimum conditions (<jats:inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" id="M1"><mtext>pH</mtext><mo>=</mo><mn>7</mn><mo>;</mo><mi>T</mi><mo>=</mo><msup><mrow><mn>25</mn></mrow><mrow><mo>°</mo></mrow></msup><mtext>C</mtext></math></jats:inline-formula>). The pseudo-first-order (PFO), pseudo-second-order (PSO), and Elovich models were fitted to the kinetic data, the yielded <jats:inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" id="M2"><msup><mrow><mi>R</mi></mrow><mrow><mn>2</mn></mrow></msup></math></jats:inline-formula> value of 0.9993 (PSO) for CF and 0.9994 (PSO) for CG which is greater than the other two models, which signify that the adsorption process is chemisorption. Thermodynamic studies show that barium adsorption using CF and CG adsorbents is endothermic. The as-fabricated CuFe2O4/rGO nanocomposite represents a propitious candidate for the removal of heavy metal ions from aqueous solutions.</jats:p>