| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Bund, Andreas
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2024A Novel Method for Preparation of Al–Ni Reactive Coatings by Incorporation of Ni Nanoparticles into an Al Matrix Fabricated by Electrodeposition in AlCl<sub>3</sub>:1‐Eethyl‐3‐Methylimidazolium Chloride (1.5:1) Ionic Liquid Containing Ni Nanoparticles
- 2024Integration of Multijunction Absorbers and Catalysts for Efficient Solar‐Driven Artificial Leaf Structures: A Physical and Materials Science Perspectivecitations
- 2023Analysis of Pre-Treatment Processes to Enable Electroplating on Nitrided Steel
- 2023Electrochemical reduction of tantalum and titanium halides in 1-butyl-1-methylpyrrolidinium bis (trifluoromethyl-sulfonyl)imide and 1-butyl-1-methylpyrrolidinium trifluoromethanesulfonate ionic liquids
- 2023Quasi-in-Situ Analysis of Electropolished Additively Manufactured Stainless Steel Surfaces
- 2022Hollow platinum-gold and palladium-gold nanoparticles: synthesis and characterization of composition-structure relationshipcitations
- 2022Corrosion Properties of Ni-P-B Dispersion Coating for Industrial Knives and Bladescitations
- 2022Selective Metallization of Polymers: Surface Activation of Polybutylene Terephthalate (PBT) Assisted by Picosecond Laser Pulsescitations
- 2021Selective metallization of polymers: surface activation of polybutylene terephthalate (PBT) assisted by picosecond laser pulsescitations
- 2021The need for digitalisation in electroplating – How digital approaches can help to optimize the electrodeposition of chromium from trivalent electrolytes
- 2021Anti-corrosive siloxane coatings for improved long-term performance of supercapacitors with an aqueous electrolytecitations
- 2021Analysis of the physical and photoelectrochemical properties of c-Si(p)/a-SiC:H(p) photocathodes for solar water splittingcitations
- 2020Aluminium-poly(3,4-ethylenedioxythiophene) rechargeable battery with ionic liquid electrolytecitations
- 2019Relation between color and surface morphology of electrodeposited chromium for decorative applicationscitations
- 2019Fluidic self-assembly on electroplated multilayer solder bumps with tailored transformation imprinted melting pointscitations
- 2019Electrochemical deposition of silicon from a sulfolane-based electrolyte: effect of applied potentialcitations
- 2019Nanoscale morphological changes at lithium interface, triggered by the electrolyte composition and electrochemical cyclingcitations
- 2018Structure and formation of trivalent chromium conversion coatings containing cobalt on zinc plated steelcitations
- 2017An electrochemical quartz crystal microbalance study on electrodeposition of aluminum and aluminum-manganese alloyscitations
- 2016Ultrasound assisted electrodeposition of Zn and Zn-TiO2 coatingscitations
- 2012Electrochemical supercapacitors based on a novel graphene/conjugated polymer composite systemcitations
- 2010Do solvation layers of ionic liquids influence electrochemical reactions?citations
- 2009Novel amino-acid-based polymer/multi-walled carbon nanotube bio-nanocompositescitations
Places of action
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article
Nanoscale morphological changes at lithium interface, triggered by the electrolyte composition and electrochemical cycling
Abstract
Understanding the electrochemical and morphological properties of the Li-electrolyte interface plays a central role in the implementation of metallic Li in safe and efficient electrochemical energy storage. The current study explores the influence of soluble polysulfides (PS) and lithium nitrate on the characteristics of the solid electrolyte interphase (SEI) layer, formed spontaneously on the Li surface, prior to electrochemical cycling. Special attention is paid to the evolution of the electrochemical impedance and nanoscale morphology of the interface, influenced by the contact time and electrolyte composition. The basic tools applied in this investigation are electrochemical impedance spectroscopy (EIS), atomic force microscopy (AFM) performed at the nanoscale, and X-ray photoelectron spectroscopy (XPS). The individual addition of polysulfides and lithium nitrate increases the interface resistance, while the simultaneous application of these components is beneficial, reducing the SEI resistive behavior. The electrochemical cycling of Li in nonmodified 1,2-dimethoxy ethane (DME) and tetraethylene glycol dimethyl ether (TEGDME) based electrolytes leads to slight morphological changes, compared to the pristine Li pattern. In contrast, we found that in the presence of PS and lithium nitrate, the interface displays a rough and inhomogeneous morphology.