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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Norkus, Eugenijus
Center for Physical Sciences and Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (30/30 displayed)
- 2024The Dependence of NiMo/Cu Catalyst Composition on Its Catalytic Activity in Sodium Borohydride Hydrolysis Reactionscitations
- 2024Hydrogen and Oxygen Evolution on Flexible Catalysts Based on Nickel–Iron Coatings
- 2024Electrolessly Deposited Cobalt–Phosphorus Coatings for Efficient Hydrogen and Oxygen Evolution Reactions
- 2023Investigation of Hydrogen and Oxygen Evolution on Cobalt-Nanoparticles-Supported Graphitic Carbon Nitridecitations
- 2023Three-dimensional Au(NiMo)/Ti catalysts for efficient oxygen evolution reaction
- 2023Black Liquor and Wood Char-Derived Nitrogen-Doped Carbon Materials for Supercapacitorscitations
- 2023Hydrogen production on CoFe, CoFeMn and CoFeMo coatings deposited on Ni foam via electroless metal platingcitations
- 2023Non-Precious Metals Catalysts for Hydrogen Generationcitations
- 2022Three-Dimensional Au(NiMo)/Ti Catalysts for Efficient Hydrogen Evolution Reactioncitations
- 2022Comparison of the Activity of 3D Binary or Ternary Cobalt Coatings for Hydrogen and Oxygen Evolution Reactionscitations
- 2021Terahertz Photoconductivity Spectra of Electrodeposited Thin Bi Filmscitations
- 2021One-Pot Microwave-Assisted Synthesis of Graphene-Supported PtCoM (M = Mn, Ru, Mo) Catalysts for Low-Temperature Fuel Cellscitations
- 2021Synthesis of Carbon-Supported MnO2 Nanocomposites for Supercapacitors Applicationcitations
- 2020Investigation of Glucose Oxidation on Gold Nanocrystallites Modified Cobalt and Cobalt-Boron Coatings
- 2020Carbon supported manganese(IV)–cobalt(II/III) oxides nanoparticles for high-performance electrochemical supercapacitors
- 2020Investigation of stability of gold nanoparticles modified zinc–cobalt coating in an alkaline sodium borohydride solutioncitations
- 2020Investigation of electro-oxidation of glucose at gold nanoparticles/carbon composites prepared in the presence of halide ionscitations
- 2020Hydrogen Generation from an Alkaline NaBH<sub>4</sub> Solution Using Different Cobalt Catalysts
- 2020Laser-Induced Selective Electroless Plating on PC/ABS Polymer: Minimisation of Thermal Effects for Supreme Processing Speedcitations
- 2020Surfactant-assisted microwave synthesis of carbon supported MnO2 nanocomposites and their application for electrochemical supercapacitorscitations
- 2019Investigation of glucose electro-oxidation on Co and CoB alloy coatings modified with Au nanoparticlescitations
- 2019Comparison of electrocatalytic activity for glucose electrooxidation of gold nanoparticles fabricated by different methodscitations
- 2018Percolation effect of a Cu layer on a MWCNT/PP nanocomposite substrate after laser direct structuring and autocatalytic platingcitations
- 2018Wood-Based Carbon Materials Modified with Cobalt Nanoparticles As Catalysts for Oxygen Reduction and Hydrogen Oxidation
- 2016Platinum-Niobium(V) Oxide/Carbon Nanocomposites Prepared By Microwave Synthesis For Ethanol Oxidation
- 2016Comparative Study of Electroless Platinum Deposition Using Multivalent Metal Ions or Hydrazine As Reducing Agents
- 2016Electroless Deposition of Cobalt-Tungsten-Boron Films from Glycine Containing Solutions As Barrier Layer Against Cu Diffusion
- 2016Colour-Difference Measurement Method for Evaluation of Quality of Electrolessly Deposited Copper on Polymer after Laser-Induced Selective Activationcitations
- 2014Investigation of Borohydride Oxidation on Graphene Supported Gold-Copper Nanocomposites
- 2014Electroless Co-B-P-W Deposition Using DMAB as Reducing Agent
Places of action
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article
Wood-Based Carbon Materials Modified with Cobalt Nanoparticles As Catalysts for Oxygen Reduction and Hydrogen Oxidation
Abstract
<jats:p>In the present study, wood-based carbon materials were investigated as catalysts for the electro-reduction of oxygen (ORR) and electro-oxidation of hydrogen (HOR) in an alkaline medium. Activated wood-based carbon and black liqueur were doped with cheap nitrogen precursor, dicyandiamide (DCDA) and were modified with cobalt nanoparticles. The doping was done by pyrolysing samples at 800 °C in the presence of DCDA. The cobalt nanoparticles were deposited on the the N-doped wood-based carbon and N-doped black liqueur using morpholine borane as a reducing agent. The synthesized catalysts were characterized using TEM, XPS, Raman Spectroscopy and ICP-OES. For electrochemical measurements, the glassy carbon (GC) electrodes were modified with synthesized catalysts and the experiments were carried out in 0.1 M KOH solution employing rotating disk electrode (RDE) method. For modifying the electrodes, a suspension (4 mg ml<jats:sup>–1</jats:sup>) was made in 2% polyvinylidenefluoride in N-methyl-2-pyrrolydone solution. </jats:p><jats:p>It was found that the N-doped wood-based carbon and N-doped black liqueur samples modified with cobalt nanoparticles show good activity for oxygen reduction and hydrogen oxidation. The combination of metal nanoparticles and N-doped wood-based carbon and N-doped black liqueur opens up new possibilities for design of the next generation catalysts. </jats:p><jats:p><jats:bold>Acknowledgment</jats:bold></jats:p><jats:p>This research was funded by a grant (M-ERA.NET-1/2016) from the Research Council of Lithuania. The author’s research was performed in cooperation with the University of Tartu (Estonia), Latvian State Institute of Wood Chemistry (Latvia) and Horizon Pulp&Paper Ltd (Estonia) under the M-ERA.NET 2 project “Wood-based Carbon Catalysts for Low-temperature Fuel Cells (WoBaCat)“ (reg. No. project3213).</jats:p>