| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Kepenienė, Virginija
Center for Physical Sciences and Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2024The Dependence of NiMo/Cu Catalyst Composition on Its Catalytic Activity in Sodium Borohydride Hydrolysis Reactionscitations
- 2023Non-Precious Metals Catalysts for Hydrogen Generationcitations
- 2022Comparison of the Activity of 3D Binary or Ternary Cobalt Coatings for Hydrogen and Oxygen Evolution Reactionscitations
- 2021One-Pot Microwave-Assisted Synthesis of Graphene-Supported PtCoM (M = Mn, Ru, Mo) Catalysts for Low-Temperature Fuel Cellscitations
- 2020Investigation of Glucose Oxidation on Gold Nanocrystallites Modified Cobalt and Cobalt-Boron Coatings
- 2020Investigation of electro-oxidation of glucose at gold nanoparticles/carbon composites prepared in the presence of halide ionscitations
- 2019Investigation of glucose electro-oxidation on Co and CoB alloy coatings modified with Au nanoparticlescitations
- 2018Wood-Based Carbon Materials Modified with Cobalt Nanoparticles As Catalysts for Oxygen Reduction and Hydrogen Oxidation
- 2016Platinum-Niobium(V) Oxide/Carbon Nanocomposites Prepared By Microwave Synthesis For Ethanol Oxidation
Places of action
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article
Wood-Based Carbon Materials Modified with Cobalt Nanoparticles As Catalysts for Oxygen Reduction and Hydrogen Oxidation
Abstract
<jats:p>In the present study, wood-based carbon materials were investigated as catalysts for the electro-reduction of oxygen (ORR) and electro-oxidation of hydrogen (HOR) in an alkaline medium. Activated wood-based carbon and black liqueur were doped with cheap nitrogen precursor, dicyandiamide (DCDA) and were modified with cobalt nanoparticles. The doping was done by pyrolysing samples at 800 °C in the presence of DCDA. The cobalt nanoparticles were deposited on the the N-doped wood-based carbon and N-doped black liqueur using morpholine borane as a reducing agent. The synthesized catalysts were characterized using TEM, XPS, Raman Spectroscopy and ICP-OES. For electrochemical measurements, the glassy carbon (GC) electrodes were modified with synthesized catalysts and the experiments were carried out in 0.1 M KOH solution employing rotating disk electrode (RDE) method. For modifying the electrodes, a suspension (4 mg ml<jats:sup>–1</jats:sup>) was made in 2% polyvinylidenefluoride in N-methyl-2-pyrrolydone solution. </jats:p><jats:p>It was found that the N-doped wood-based carbon and N-doped black liqueur samples modified with cobalt nanoparticles show good activity for oxygen reduction and hydrogen oxidation. The combination of metal nanoparticles and N-doped wood-based carbon and N-doped black liqueur opens up new possibilities for design of the next generation catalysts. </jats:p><jats:p><jats:bold>Acknowledgment</jats:bold></jats:p><jats:p>This research was funded by a grant (M-ERA.NET-1/2016) from the Research Council of Lithuania. The author’s research was performed in cooperation with the University of Tartu (Estonia), Latvian State Institute of Wood Chemistry (Latvia) and Horizon Pulp&Paper Ltd (Estonia) under the M-ERA.NET 2 project “Wood-based Carbon Catalysts for Low-temperature Fuel Cells (WoBaCat)“ (reg. No. project3213).</jats:p>