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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Niaura, Gediminas
Center for Physical Sciences and Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2023Investigation of Hydrogen and Oxygen Evolution on Cobalt-Nanoparticles-Supported Graphitic Carbon Nitridecitations
- 2023Black Liquor and Wood Char-Derived Nitrogen-Doped Carbon Materials for Supercapacitorscitations
- 2022Wet Synthesis of Graphene-Polypyrrole Nanocomposites via Graphite Intercalation Compoundscitations
- 2022Design and Characterization of Nanostructured Titanium Monoxide Films Decorated with Polyaniline Speciescitations
- 2022Green Removal of DUV-Polarity-Modified PMMA for Wet Transfer of CVD Graphenecitations
- 2022Structural Control and Electrical Behavior of Thermally Reduced Graphene Oxide Samples Assisted with Malonic Acid and Phosphorus Pentoxidecitations
- 2022Synthesis and Characterization of Graphite Intercalation Compounds with Sulfuric Acidcitations
- 2022The direct growth of planar and vertical graphene on Si(100) <i>via</i> microwave plasma chemical vapor deposition: synthesis conditions effectscitations
- 2018Wood-Based Carbon Materials Modified with Cobalt Nanoparticles As Catalysts for Oxygen Reduction and Hydrogen Oxidation
- 2017AlAs as a Bi blocking barrier in GaAsBi multi-quantum wells: Structural analysiscitations
Places of action
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article
Wood-Based Carbon Materials Modified with Cobalt Nanoparticles As Catalysts for Oxygen Reduction and Hydrogen Oxidation
Abstract
<jats:p>In the present study, wood-based carbon materials were investigated as catalysts for the electro-reduction of oxygen (ORR) and electro-oxidation of hydrogen (HOR) in an alkaline medium. Activated wood-based carbon and black liqueur were doped with cheap nitrogen precursor, dicyandiamide (DCDA) and were modified with cobalt nanoparticles. The doping was done by pyrolysing samples at 800 °C in the presence of DCDA. The cobalt nanoparticles were deposited on the the N-doped wood-based carbon and N-doped black liqueur using morpholine borane as a reducing agent. The synthesized catalysts were characterized using TEM, XPS, Raman Spectroscopy and ICP-OES. For electrochemical measurements, the glassy carbon (GC) electrodes were modified with synthesized catalysts and the experiments were carried out in 0.1 M KOH solution employing rotating disk electrode (RDE) method. For modifying the electrodes, a suspension (4 mg ml<jats:sup>–1</jats:sup>) was made in 2% polyvinylidenefluoride in N-methyl-2-pyrrolydone solution. </jats:p><jats:p>It was found that the N-doped wood-based carbon and N-doped black liqueur samples modified with cobalt nanoparticles show good activity for oxygen reduction and hydrogen oxidation. The combination of metal nanoparticles and N-doped wood-based carbon and N-doped black liqueur opens up new possibilities for design of the next generation catalysts. </jats:p><jats:p><jats:bold>Acknowledgment</jats:bold></jats:p><jats:p>This research was funded by a grant (M-ERA.NET-1/2016) from the Research Council of Lithuania. The author’s research was performed in cooperation with the University of Tartu (Estonia), Latvian State Institute of Wood Chemistry (Latvia) and Horizon Pulp&Paper Ltd (Estonia) under the M-ERA.NET 2 project “Wood-based Carbon Catalysts for Low-temperature Fuel Cells (WoBaCat)“ (reg. No. project3213).</jats:p>