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| Naji, M. |
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Sun, Lina
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Publications (3/3 displayed)
- 2018Switching of Dye Loading Mechanism in Electrochemical Self-Assembly of CuSCN-DAST Hybrid Thin Films
- 2018Electrochemical Self-Assembly of CuSCN / Dye Hybrid Thin Films and Their Optical Properties
- 2017Oxygen Reduction Reaction As the Essential Process for Cathodic Electrodeposition of Metal Oxide Thin Films
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article
Oxygen Reduction Reaction As the Essential Process for Cathodic Electrodeposition of Metal Oxide Thin Films
Abstract
<jats:p><jats:bold>1. </jats:bold><jats:bold>Introduction </jats:bold></jats:p><jats:p> Oxygen reduction reaction (ORR) has frequently been employed to electrodeposit metal oxide thin films [1-4]. ORR can often be limited by mass transport of oxygen because of its low solubility in water. It is therefore important to precisely grasp bulk concentration of O<jats:sub>2</jats:sub> and its diffusion in a wide temperature range. Optically transparent electrodes such as F-doped SnO<jats:sub>2</jats:sub> (FTO) coated glass is often used as the substrate for the purpose of thin film characterization and device fabrication. So it is important to understand the kinetics of such electrodes for the ORR. In this study, we have carried out hydrodynamic electrochemical analysis employing rotating disk Pt and FTO electrodes (RDEs) to quantify each of these limiting factors.<jats:p>[1] T. Yoshida, K. Terada, D. Schlettwein, T. Oekermann, T. Sugiura, H. Minoura, Adv. Mater. 2000, 12, 1214. </jats:p><jats:p>[2] T. Yoshida, T. Oekermann, K. Okabe, D. Schlettwein, K. Funabiki, H. Minoura, Electrochemistry 2002, 70, 470. </jats:p><jats:p>[3] A. Goux, T. Pauporté, T. Yoshida, D. Lincot, Langmuir 2006, 22, 10 545. </jats:p><jats:p>[4] T. Yoshida, J. Zhang, D. Komatsu, S. Sawatani, H. Minoura, T. Pauporté, D. Lincot, T. Oekermann, D. Schlettwain, H. Tada, D. Wöhrle, K. Funabiki, M. Matsui, H. Miura and H. Yanagi, Adv. Func. Mater. 2009, 19, 17.</jats:p><jats:p></jats:p><jats:p><jats:inline-formula><jats:inline-graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="916fig1.jpeg" xlink:type="simple" /></jats:inline-formula></jats:p><jats:p>Figure 1</jats:p><jats:p />