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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Payne, Julia Louise
University of St Andrews
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2023Manipulation of structure and optoelectronic properties through bromine inclusion in a layered lead bromide perovskitecitations
- 2022Synthesis, structure and tunability of zero dimensional organic-inorganic metal halides utilising the m-xylylenediammonium cation: MXD2PbI6, MXDBiI5, and MXD3Bi2Br12·2H2Ocitations
- 2021Time-resolved in-situ X-ray diffraction study of CaO and CaO:Ca3Al2O6 composite catalysts for biodiesel productioncitations
- 2021Use of interplay between A-site non-stoichiometry and hydroxide doping to deliver novel proton-conducting perovskite oxidescitations
- 2020Bandgap bowing in a zero-dimensional hybrid halide perovskite derivativecitations
- 2018Transition metal chlorides NiCl2, KNiCl3, Li6VCl8 and Li2MnCl4 as alternative cathode materials in primary Li thermal batteriescitations
- 2017Charge carrier localised in zero-dimensional (CH 3 NH 3 ) 3 Bi 2 1 9 clusterscitations
- 2017Charge carrier localised in zero-dimensional (CH3NH3)3Bi219 clusterscitations
- 2017Charge carrier localised in zero-dimensional (CH3NH3)3Bi219 clusterscitations
- 2017Synthesis and electrochemical study of CoNi2S4 as a novel cathode material in a primary Li thermal batterycitations
- 2016Zirconium trisulfide as a promising cathode material for Li primary thermal batteriescitations
Places of action
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article
Zirconium trisulfide as a promising cathode material for Li primary thermal batteries
Abstract
In this work ZrS<sub>3</sub> has been synthesized by solid state reaction in a sealed quartz tube and investigated as a candidate cathode material in Li thermal batteries. The structure of ZrS<sub>3</sub> before and after cell testing has been studied using powder X-ray diffraction. A new spinel related material, LiZr<sub>2</sub>S<sub>4</sub>, has been identified as the product of the electrochemical process, which can be indexed to a = 10.452(8) Å cubic unit cell. The electrochemical properties of the batteries were investigated at 500 °C against Li<sub>13</sub>Si<sub>4</sub> by galvanostatic discharge and galvanostatic intermittent titration technique (GITT). In a thermal Li cell at 500 °Ca single voltage plateau of 1.70 V at a current density of 11 mA/cm<sup>2</sup> was achieved with capacity of 357 mA h g<sup>-1</sup>. Therefore ZrS<sub>3</sub> material has some promise as a cathode for Li thermal batteries.