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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Werchmeister, Rebecka Maria Larsen
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2019Three-Dimensional Sulfite Oxidase Bioanodes Based on Graphene Functionalized Carbon Paper for Sulfite/O2 Biofuel Cellscitations
- 2019Three-Dimensional Sulfite Oxidase Bioanodes Based on Graphene Functionalized Carbon Paper for Sulfite/O2 Biofuel Cellscitations
- 2019Three-dimensional bioelectrodes utilizing graphene based bioinkcitations
- 2019Three-dimensional sulfite oxidase bioanodes based on graphene functionalized carbon paper for sulfite/O-2 biofuel cellscitations
- 2014Removal of NO x with Porous Cell Stacks with La 0.85 Sr0.15Co x Mn 1-x O 3+δ -Ce 0.9 Gd 0.1 O 1.95 Electrodes Infiltrated with BaOcitations
- 2014Removal of NOx with Porous Cell Stacks with La0.85Sr0.15CoxMn1-xO3+δ-Ce0.9Gd0.1O1.95 Electrodes Infiltrated with BaOcitations
- 2010Characterization of (La 1-x Sr x )(s)MnO 3 and Doped Ceria Composite Electrodes in NO x -Containing Atmosphere with Impedance Spectroscopycitations
- 2010Characterization of (La1-xSrx)(s)MnO3 and Doped Ceria Composite Electrodes in NOx-Containing Atmosphere with Impedance Spectroscopycitations
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article
Removal of NOx with Porous Cell Stacks with La0.85Sr0.15CoxMn1-xO3+δ-Ce0.9Gd0.1O1.95 Electrodes Infiltrated with BaO
Abstract
Porous cell stacks with composite electrodes of La<sub>0.85</sub>Sr<sub>0.15</sub>Co<sub>x</sub>Mn<sub>1-x</sub>O<sub>3</sub>-Ce<sub>0.9</sub>Gd<sub>0.1</sub>O<sub>1.95</sub> were tested for activity toward selective electrochemical reduction of NO<sub>x</sub> to N<sub>2</sub> in the presence of 10% O<sub>2</sub>. The cell stacks were produced by tape casting, laminating and sintering the backbone structure followed by infiltration with BaO or La<sub>0.85</sub>Sr<sub>0.15</sub>MnO<sub>3+δ</sub>. The cell stacks were tested in an atmosphere of 1000 ppm NO or NO<sub>2</sub> + 10% O<sub>2</sub> in Ar with 10% O<sub>2</sub> in Ar as reference, and in the temperature range of 250 to 500 °C. The cell stacks were investigated electrochemically with cyclic voltammetry and polarization, and the outlet gas composition was monitored. Doping with Co increases the electrodes activity for reducing NO<sub>x</sub>, and up to 93% conversion in the presence of 10% O<sub>2</sub> at 400 °C was measured. Infiltration with BaO was necessary to achieve any formation of N<sub>2</sub>. Square wave polarization increased the activity of the electrodes achieving a current efficiency as high as 20% at 350 °C, and this indicates a problem with mass transfer. An atmosphere containing NO<sub>2</sub> also increased the activity of the electrodes, which points to a mechanism with a NO<sub>2</sub> related intermediate. © 2014 The Electrochemical Society. All rights reserved.