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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Sažinas, Rokas
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Publications (7/7 displayed)
- 2023Continuous-flow electrosynthesis of ammonia by nitrogen reduction and hydrogen oxidationcitations
- 2023Continuous-flow electrosynthesis of ammonia by nitrogen reduction and hydrogen oxidationcitations
- 2019Silver Modified Cathodes for Solid Oxide Fuel Cellscitations
- 2019Silver Modified Cathodes for Solid Oxide Fuel Cellscitations
- 2019Surface reactivity and cation non-stoichiometry in BaZr 1−x Y x O 3−δ (x = 0–0.2) exposed to CO 2 at elevated temperaturecitations
- 2018Novel Processing of Cathodes for Solid Oxide Fuel Cells
- 2017Stability and cation diffusion in BaZrO3-based proton conducting solid state electrolytes
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article
Silver Modified Cathodes for Solid Oxide Fuel Cells
Abstract
La<sub>1-x-y</sub>Sr<sub>x</sub>Ag<sub>y</sub>MnO<sub>3-δ</sub> was synthesized via modified Pechini method. Silver (Ag) was incorporated into La<sub>1-x-y</sub>Sr<sub>x</sub>Ag<sub>y</sub>MnO<sub>3-δ</sub> cathode material for solid oxide fuel cells as a catalyst precursor for oxygen reduction reaction. The La<sub>1-x-y</sub>Sr<sub>x</sub>Ag<sub>y</sub>MnO<sub>3-δ</sub>perovskite single phase formed at 800°C, and the solubility of Ag inthe crystal lattice of the perovskite was up to 5 mol%.The single-phase materials revealed thermalstability in different oxidizing atmospheres up to sintering temperatureof thecathode at 1050°C. The exsolution of the metallicAg nanoparticles was performed at 350–600°C in reducing atmosphere.Scanningelectron and scanning transmission electronmicrocopy revealed a good mechanical contact of the Ag nanoparticles tothe surfaceof the perovskite after reducing conditions. Theelectrochemical tests of the materials showed a good electrocatalyticeffectof nanosized Ag toward oxygen reduction reaction.The electrochemical performance of the cathodes revealed the dependenceon electrolyte material and exsolution time.