| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Pereira, Cm
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Topics
Publications (12/12 displayed)
- 2022Molecularly imprinted polymer as a synthetic antibody for the biorecognition of hazelnut Cor a 14-allergencitations
- 2021A Disposable Saliva Electrochemical MIP-Based Biosensor for Detection of the Stress Biomarker α-Amylase in Point-of-Care Applicationscitations
- 2018Electrodeposition of an ultrathin TiO2 coating using a deep eutectic solvent based on choline chloridecitations
- 2017Electrodeposition of Mn and Mn-Sn Alloy Using Choline Chloride-Based Ionic Liquidscitations
- 2017Zinc Electrodeposition from deep eutectic solvent containing organic additivescitations
- 2017Electrodeposition of Co and Co composites with carbon nanotubes using choline chloride-based ionic liquidscitations
- 2017Electrochemical detection of cardiac biomarker myoglobin using polyphenol as imprinted polymer receptorcitations
- 2016Metal cation sorption ability of immobilized and reticulated chondroitin sulfate or fucoidan through a sol-gel crosslinking schemecitations
- 2015Influence of Amines on the Electrodeposition of Zn-Ni Alloy from a Eutectic-Type Ionic Liquidcitations
- 2015Polymer composite materials modified with nano-oxides and phosphinates hybrid flame retardant systemscitations
- 2011Preparation and characterization of DNA films using oleylamine modified Au surfacescitations
- 2009Dielectric Relaxation and Optical Transmittance of PVC Membranes Modified by Nematic Liquid Crystal
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article
Influence of Amines on the Electrodeposition of Zn-Ni Alloy from a Eutectic-Type Ionic Liquid
Abstract
Zn alloys are considered an alternative to replace Cd in protective coatings. Among Zn alloys, Zn-Ni are those with the higher corrosion resistance and better mechanical characteristics. Although Zn-Ni alloy can be electrodeposited from eutectic-type ionic liquid the morphology of the deposits needs to be improved. The effect of ethylamine and ethylenediamine on the electrodeposition of Zn-Ni alloy was investigated from a eutectic-type ionic liquid (ethaline). The presence of the amines in the plating bath modified the CV and j-t profiles. The nucleation mechanism was also influenced by adding the amines to the solution and the deposition of Zn-Ni in the presence of ethylenediamine followed the 3D progressive mechanism. Electrodeposition of Zn-Ni alloy from ethaline gives origin to a deposit with small grain particles with partial coverage of the electrode. Using the same electrodeposition conditions, the addition of amines allowed the full coverage of the electrode surface. In the presence of ethylamine deposit was formed by globular particles and by hexagonal platelets for deposits obtained in the presence ethylenediamine. Corrosion of the Zn-Ni metallic films was evaluated by potentiodynamic polarization experiments. The lowest value for the corrosion potential was obtained for the deposit prepared in the presence of ethylenediamine.