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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Mamme, Mesfin Haile
Vrije Universiteit Brussel
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (6/6 displayed)
- 2024Study of Solid-State Diffusion Impedance in Li-Ion Batteries Using Parallel-Diffusion Warburg Modelcitations
- 2023Assessing the Reactivity of the Na3PS4 Solid-State Electrolyte with the Sodium Metal Negative Electrode Using Total Trajectory Analysis with Neural-Network Potential Molecular Dynamicscitations
- 2020The role of hydrogen bond donor and water content on the electrochemical reduction of Ni2+ from solvents - an experimental and modelling studycitations
- 2019Numerical interpretation to differentiate hydrogen trapping effects in iron alloys in the Devanathan-Stachurski permeation cellcitations
- 2019Electrodeposition of Nickel Based Nanostructures from Deep Eutectic Solvent / Water Mixtures As Electrocatalysts for the Oxygen Evolution Reaction
- 2018Numerical insights into the early stages of nanoscale electrodeposition: nanocluster surface diffusion and aggregative growthcitations
Places of action
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article
Study of Solid-State Diffusion Impedance in Li-Ion Batteries Using Parallel-Diffusion Warburg Model
Abstract
Anomalous diffusion impedance due to the solid-state Li+ diffusion in Li-ion batteries is often troublesome for the analysis. In this work, we propose a novel analytical Parallel-diffusion Warburg (PDW) model and couple it with the conventional equivalent electrical circuit model (EECM) analysis to tackle this long-standing challenge. The analytical expression of the PDW is derived from the classical Fickian diffusion framework, introducing non-unified diffusion coefficients that originate from the diverse crystalline conditions of Li+ diffusion paths, as theoretically demonstrated in the atomistic modeling results. The proposed approach (EECM + PDW) is successfully employed to study the diffusion impedance of thin-film LiNi0.5Mn1.5O4 (LNMO) electrodes and porous LiNi0.80Co0.15Al0.05O2 (NCA) electrodes, demonstrating the applicability and robustness of this method.