• Nash, William
• Monrrabal, Gleidys
• Landgraf, Steffen
• Weber, Norbert
• Lappan, Tobias
• Weier, Tom
• Sarma, Martins
• Shevchenko, Natalia
• Trtik, Pavel
• Lee, Juhan

Abstract

<jats:title>Abstract</jats:title><jats:p>This paper presents the cycling of a novel low-cost Na-Zn liquid metal battery. Its 600°C operating temperature presents multiple challenges that must be overcome to achieve commercial viability, both from a structural and electrochemical perspective. To enable long-term cycling of the Na-Zn battery in realistic environment, we have developed a reusable, hermetically sealed, high temperature and sufficiently corrosion resistant cell concept. The design as well as various approaches for assembling and filling the cell are presented. The factors considered when selecting specific components are documented and explained. The active volume of the cell design can be up to 40 mL, corresponding to a nominal capacity of 1 A h, while the entire cell body weighs around 800 g and costs approximately €200 ($215). The performance of the cell is demonstrated in terms of longevity (1000 h) and high discharge current density (100 mA m<jats:sup>-2</jats:sup>). The manuscript not only presents the first long-term cycling performance of the novel Na-Zn chemistry achieving Coulombic efficiency of up to 80%, but also demonstrates the design's versatility with in situ dynamic neutron radiography of the cell.</jats:p>

Topics

• density
• impedance spectroscopy
• corrosion
• current density