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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Naujokaitis, Arnas
Center for Physical Sciences and Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2023Aluminum Anodizing in an Aqueous Solution of Formic Acid with Ammonium Heptamolybdate Additivecitations
- 2023Effect of Oxalic Acid Additives on Aluminum Anodizing in Formic Acid Containing Ammonium Heptamolybdatecitations
- 2022Design and Characterization of Nanostructured Titanium Monoxide Films Decorated with Polyaniline Speciescitations
- 2022Seed Layer Optimisation for Ultra-Thin Sb2Se3 Solar Cells on TiO2 by Vapour Transport Depositioncitations
- 2020Atomic-Resolution EDX, HAADF, and EELS Study of GaAs1-xBix Alloyscitations
- 2020Suppression of Electric Field-Induced Segregation in Sky-Blue Perovskite Light-Emitting Electrochemical Cellscitations
- 2019Electronic structure of CsPbBr<sub>3−x</sub>Cl<sub>x</sub> perovskites: synthesis, experimental characterization, and DFT simulationscitations
- 2019A few-minute synthesis of CsPbBr3 nanolasers with a high quality factor by spraying at ambient conditionscitations
- 2019A few-minute synthesis of CsPbBr 3 nanolasers with a high quality factor by spraying at ambient conditionscitations
- 2016Comparative Study of Electroless Platinum Deposition Using Multivalent Metal Ions or Hydrazine As Reducing Agents
- 2016Electroless Deposition of Cobalt-Tungsten-Boron Films from Glycine Containing Solutions As Barrier Layer Against Cu Diffusion
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article
Effect of Oxalic Acid Additives on Aluminum Anodizing in Formic Acid Containing Ammonium Heptamolybdate
Abstract
<jats:p>This paper reports a systematic study of the role of oxalic acid additives in aluminum anodizing in formic acid containing ammonium heptamolybdate. Adding oxalic acid in a concentration range of 5–20 mM to the 0.4 M formic acid solution containing 0.03 M ammonium heptamolybdate improves anodic film growth, increasing the film thickness and smoothing strongly wavy interface between the film and aluminum, and adding 100 mM of oxalic acid results in an almost complete block of the regular anodic film formation. In the case of aluminum anodizing in formic acid, the ammonium heptamolybdate additive prevents aluminum dissolution more effectively than only oxalic acid. The role of oxalic acid in this process is only to improve film growth and morphology. However, ammonium heptamolybdate improves film growth by increasing its thickness. Linear sweep voltammetry studies combined with SEM investigations of alumina growth show that in heptamolybdate-containing electrolytes, a thin porous alumina film is formed at the beginning of the process. Then, when the electrolyte oxidation potential is reached, the thin film on the surface breaks, resulting in a significant increase in the anodizing surface, and anodic oxide begins to grow rapidly.</jats:p>