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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Toppare, Levent
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Publications (4/4 displayed)
- 2024Design, Synthesis, and Theoretical Studies on the Benzoxadiazole and Thienopyrrole Containing Conjugated Random Copolymers for Organic Solar Cell Applicationscitations
- 2023Structure-Electrochemical Property Relationship of F vs 2F Substituents in Low Bandgap Conjugated Polymerscitations
- 2015A benzimidazole-based conducting polymer and a PMMA–clay nanocomposite containing biosensor platform for glucose sensingcitations
- 2013Effective and functional surface design for biosensing applications based on a novel conducting polymer and PMMA/clay nanocompositecitations
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article
Structure-Electrochemical Property Relationship of F vs 2F Substituents in Low Bandgap Conjugated Polymers
Abstract
<jats:p>Two alternating copolymers bearing fluorinated benzothiadiazole as a strong acceptor unit and dithienopyrrole as a strong donor unit were designed and synthesized to discuss the effect of the number of fluorine atom substitution. The polymers were characterized via cyclic voltammetry, spectroelectrochemistry, electrochemical impedance spectroscopy and galvanostatic charge discharge studies. Besides a red shift in absorption spectra, an anodic shift was also observed in the oxidation potentials when number of fluorine atom increases in the polymer backbone. Galvanostatic charge-discharge (GCD) studies revealed that difluorinated polymer exhibited enhanced area specific capacitance compared to mono fluorinated polymer.</jats:p>