| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Baker, Richard T.
University of St Andrews
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Boosting the electrochemical performance of oxygen electrodes via the formation of LSCF-BaCe 0.9–x Mo x Y 0.1 O 3–δ triple conducting composite for solid oxide fuel cells:Part IIcitations
- 2024Boosting the electrochemical performance of oxygen electrodes via the formation of LSCF-BaCe0.9–xMoxY0.1O3–δ triple conducting composite for solid oxide fuel cellscitations
- 2022Coordination-controlled electrodeposition of palladium/copper thin films onto a pyridine-terminated self-assembled monolayer
- 2020Ordered mesoporous carbon as a support for palladium-based hydrodechlorination catalystscitations
- 2018Influence of electrolytes of Li salts, EMIMBF4 and mixed phases on electrochemical and physical properties of Nafion membranecitations
- 2017Influence of electrolytes of Li salts, EMIMBF4 and mixed phases on electrochemical and physical properties of Nafion membranecitations
- 2017Influence of electrolytes of Li salts, EMIMBF 4 and mixed phases on electrochemical and physical properties of Nafion membranecitations
- 2017Effect of the synthesis conditions on the properties of La0.15Sm0.35Sr0.08Ba0.42FeO3 − δ cathode material for SOFCscitations
- 2015Structural characterisation of printable noble metal/poly(vinyl-alcohol) nanocomposites for optical applicationscitations
- 2010Improvement in the Reduction Behavior of Novel ZrO2-CeO2 Solid Solutions with a Tubular Nanostructure by Incorporation of Pdcitations
- 2009Synthesis of Nanocrystalline CeO2-ZrO2 Solid Solutions by a Citrate Complexation Route: A Thermochemical and Structural Studycitations
- 2009Structural, morphological and electrical properties of Gd0.1Ce0.9O1.95 prepared by a citrate complexation methodcitations
- 2003In situ magnetic resonance imaging of electrically-induced water diffusion in a Nafion ionic polymer filmcitations
- 2001Characterisation of the Metal Phase in NM/Ce0.68Zr0.32O2 (NM = Pt and Pd) Catalysts by Hydrogen Chemisorption and HRTEM Microscopy: A Comparative Studycitations
Places of action
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article
Coordination-controlled electrodeposition of palladium/copper thin films onto a pyridine-terminated self-assembled monolayer
Abstract
Yao Z, Naden AB, Baker RT, Buck M. Coordination-Controlled Electrodeposition of Palladium/Copper Thin Films onto a Pyridine-Terminated Self-Assembled Monolayer. Journal of the Electrochemical Society . 2022;169(11): 112515. ; A scheme for the electrodeposition of ultrathin bimetallic layers on top of a self-assembled monolayer (SAM) is investigated which combines the deposition of one metal (Pd) coordinated to a functionalized SAM (3-(4-pyridine-4-yl-phenyl)-propane-1-thiol, PyP3) on Au/mica with another metal (Cu) from the bulk electrolyte. The coordination-controlled electrodeposition (CCED) is a four-phase process comprising (i) Pd2+ coordination to the terminal pyridine units of the SAM, (ii) reduction of Pd and nanoparticle formation, (iii) formation of an intermixed shell of Pd and Cu, and (iv) deposition of bulk Cu. Chronoamperometry reveals a fast nucleation phase where Pd nanoparticles form within a few milliseconds and seed the Cu deposition. The Pd-Cu core-shell nature of deposited nanoparticles is confirmed by transmission electron microscopy (TEM). Harnessing the selective coordination of Pd2+ to PyP3, a one-pot procedure is further developed using electrolytes containing both Pd2+ and Cu2+ ions. Thus simplifying complexation and reduction, continuous Pd/Cu films are obtained in a multistep process as verified by scanning tunneling microscopy (STM). With a percolation threshold below 3 nm, CCED, as a SAM-controlled deposition strategy, offers an avenue for generation of ultrathin films.