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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Brousse, Thierry
Nantes Université
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (35/35 displayed)
- 2024Enhanced Li<sup>+</sup> and Mg<sup>2+</sup> Diffusion at the Polymer–Ionic Liquid Interface within PVDF‐Based Ionogel Electrolytes for Batteries and Metal‐Ion Capacitorscitations
- 2024Nanofeather ruthenium nitride electrodes for electrochemical capacitorscitations
- 2024Enhanced Li + and Mg 2+ Diffusion at the Polymer–Ionic Liquid Interface within PVDF‐Based Ionogel Electrolytes for Batteries and Metal‐Ion Capacitorscitations
- 2024Tuning Deposition Conditions for VN Thin Films Electrodes for Microsupercapacitors: Influence of the Thicknesscitations
- 2024Control of microstructure and composition of reactively sputtered vanadium nitride thin films based on hysteresis curves and application to microsupercapacitorscitations
- 2023Major Improvement in the Cycling Ability of Pseudocapacitive Vanadium Nitride Films for Micro‐Supercapacitorcitations
- 2023Structure and Electrochemical Properties of Bronze Phase Materials Containing Two Transition Metalscitations
- 2022Sputtered (Fe,Mn)<sub>3</sub>O<sub>4</sub> Spinel Oxide Thin Films for Micro-Supercapacitorcitations
- 2022Ag2V4O11: from primary to secondary batterycitations
- 2022Sputtered (Fe,Mn) 3 O 4 Spinel Oxide Thin Films for Micro-Supercapacitorcitations
- 2022Three-Dimensional TiO2 Film Deposited by ALD on Porous Metallic Scaffold for 3D Li-Ion Micro-Batteries: A Road towards Ultra-High Capacity Electrodecitations
- 2022Three-Dimensional TiO2 Film Deposited by ALD on Porous Metallic Scaffold for 3D Li-Ion Micro-Batteries: A Road towards Ultra-High Capacity Electrodecitations
- 2021Sodium borohydride (NaBH 4 ) as a high-capacity material for next-generation sodium-ion capacitorscitations
- 2021Influence of ion implantation on the charge storage mechanism of vanadium nitride pseudocapacitive thin filmscitations
- 2018Prototyping Aqueous Electrochemical Capacitors
- 2018Stabilizing the Structure of LiCoPO4 Nanocrystals via Addition of Fe3+: Formation of Fe3+ Surface Layer, Creation of Diffusion-Enhancing Vacancies, and Enabling High-Voltage Battery Operationcitations
- 2018On chip interdigitated micro-supercapacitors based on sputtered bifunctional vanadium nitride thin films with finely tuned inter- and intracolumnar porositiescitations
- 2018Stabilizing the Structure of LiCoPO4 Nanocrystals via Addition of Fe3+: Formation of Fe3+ Surface Layer, Creation of Diffusion-Enhancing Vacancies, and Enabling High-Voltage Battery Operation ; Stabilizing the Structure of LiCoPO4 Nanocrystals via Addition of Fe3+: Formation of Fe3+ Surface Layer, Creation of Diffusion-Enhancing Vacancies, and Enabling High-Voltage Battery Operation: Formation of Fe 3+ Surface Layer, Creation of Diffusion-Enhancing Vacancies, and Enabling High-Voltage Battery Operationcitations
- 2017Improved electro-grafting of nitropyrene onto onion-like carbon via in situ electrochemical reduction and polymerization: tailoring redox energy density of the supercapacitor positive electrodecitations
- 2017Improved electro-grafting of nitropyrene onto onion-like carbon via in situ electrochemical reduction and polymerization: tailoring redox energy density of the supercapacitor positive electrodecitations
- 2017High areal energy 3D-interdigitated micro-supercapacitors in aqueous and ionic liquid electrolytescitations
- 2017Tuning the Cation Ordering with the Deposition Pressure in Sputtered LiMn1.5Ni0.5O4 Thin Film Deposited on Functional Current Collectors for Li-Ion Microbattery Applicationscitations
- 2016Ultrafast charge–discharge characteristics of a nanosized core–shell structured LiFePO4 material for hybrid supercapacitor applicationscitations
- 2016Atomic Layer Deposition of Functional Layers for on Chip 3D Li-Ion All Solid State Microbatterycitations
- 2015Chemical modification of graphene oxide through diazonium chemistry and its influence on the structure-properties relationships of graphene oxide-iron oxide nanocompositescitations
- 2015Chemical Modification of Graphene Oxide through Diazonium Chemistry and Its Influence on the Structure-Property Relationships of Graphene Oxide-Iron Oxide Nanocompositescitations
- 2015Electrochemical Performance of Carbon/MnO2 Nanocomposites Prepared via Molecular Bridging as Supercapacitor Electrode Materialscitations
- 2014Step-conformal deposition of TiO2 and MnO2 electrodes on advanced silicon microstructures for 3D Li-ion microbatteries and micro-supercapacitors
- 2013Impact of the morphological characteristics on the supercapacitive electrochemical performances of FeOx/Reduced Graphene Oxide nanocompositescitations
- 2013Nanosilicon-based thick negative composite electrodes for lithium batteries with graphene as conductive additivecitations
- 2013Nanosilicon-Based Thick Negative Composite Electrodes for Lithium Batteries with Graphene as Conductive Additivecitations
- 2013Nanosilicon‐Based Thick Negative Composite Electrodes for Lithium Batteries with Graphene as Conductive Additivecitations
- 2012In situ redox functionalization of composite electrodes for high power-high energy electrochemical storage systems via a non-covalent approachcitations
- 2012New strategies for preparing nanocomposites as electrode materials for Li-ion batteries and electrochemical capacitors
- 2007Silicon/graphite nanocomposite electrodes prepared by low pressure chemical vapor depositioncitations
Places of action
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article
Sputtered (Fe,Mn)<sub>3</sub>O<sub>4</sub> Spinel Oxide Thin Films for Micro-Supercapacitor
Abstract
<jats:p>The scaling up of wireless operating microelectronics for upcoming Internet of Things (IoT) applications demands high-performance micro-supercapacitors (MSCs) with corresponding high-energy and power capabilities. Indeed, this necessitates the quest for MSC’s electrode materials capable of delivering high energy density at high charge/discharge rates. Many multicationic oxides, such as spinel manganese-iron compounds, demonstrate good pseudocapacitive properties as positive electrodes in conventional supercapacitors. However, fulfilling the required fabrication techniques is a challenge for their applications in MSCs. Hence, this study, for the first time, demonstrates the successful deposition of spinel Mn-Fe thin films on a functional platinum-based current collector. The deposition is achieved in a reactive oxygen environment via reactive DC magnetron sputtering techniques and subsequently annealed ex situ at 600 °C in a nitrogen environment. The electrochemical signature in neutral 1 M Na<jats:sub>2</jats:sub>SO<jats:sub>4</jats:sub> aqueous electrolyte is comparable to those reported for spinel type Mn-Fe bulk counterparts. The areal capacitance at 10 mV.s<jats:sup>−1</jats:sup> is 15.5 mF.cm<jats:sup>−2</jats:sup> for 1 <jats:italic>μ</jats:italic>m thick film, exhibiting excellent coulombic efficiency (close to 100%) and long-term cycle stability after 10,000 cycles. Thus, the synthesis of the multicationic pseudocapacitive oxides via compatible microelectronic deposition methods has set a prospective path to achieve very high-performance MSCs for future IoT applications.</jats:p><jats:p><jats:inline-formula><jats:inline-graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="jesaca050-ga.jpg" xlink:type="simple" /></jats:inline-formula></jats:p>