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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ahmadi, Majid
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (28/28 displayed)
- 2024Giant electrostriction-like response from defective non-ferroelectric epitaxial BaTiO3 integrated on Si (100)citations
- 2024Strong Substrate Influence on Atomic Structure and Properties of Epitaxial VO 2 Thin Filmscitations
- 2024Strong substrate influence on atomic structure and properties of epitaxial VO2 thin filmscitations
- 2024Domains with Varying Conductance in Tensile Strained SrMnO3 Thin Films Using Out-of-Plane Electric Fieldscitations
- 2024Domains with Varying Conductance in Tensile Strained SrMnO 3 Thin Films Using Out-of-Plane Electric Fieldscitations
- 2024Growth mechanism of oleylammonium-based tin and lead bromide perovskite nanostructurescitations
- 2024Giant electrostriction-like response from defective non-ferroelectric epitaxial BaTiO 3 integrated on Si (100)citations
- 2024Metal-Solvent Complex Formation at the Surface of InP Colloidal Quantum Dotscitations
- 2023Strong substrate influence on atomic structure and properties of epitaxial VO2 thin filmscitations
- 2023Van der Waals Epitaxy of Pulsed Laser Deposited Antimony Thin Films on Lattice-matched and Amorphous Substratescitations
- 2023Van der Waals Epitaxy of Pulsed Laser Deposited Antimony Thin Films on Lattice-matched and Amorphous Substratescitations
- 2023Effects of Intermixing in Sb2Te3/Ge1+xTe Multilayers on the Thermoelectric Power Factorcitations
- 2023Nickel Boride (Ni x B) Nanocrystals:From Solid-State Synthesis to Highly Colloidally Stable Inkscitations
- 2023Nickel Boride (NixB) Nanocrystalscitations
- 2022Phase Separation in Ge-Rich GeSbTe at Different Length Scales: Melt-Quenched Bulk versus Annealed Thin Filmscitations
- 2021Editors' Choice - Dealloying-Driven Cerium Precipitation on Intermetallic Particles in Aerospace Aluminium Alloyscitations
- 2020Locally Condensed Water as a Solution for In Situ Wet Corrosion Electron Microscopycitations
- 2020Infrared absorbance of vertically-aligned multi-walled CNT forest as a function of synthesis temperature and timecitations
- 2020How Mn/Ni Ordering Controls Electrochemical Performance in High-Voltage Spinel LiNi0.44Mn1.56O4 with Fixed Oxygen Contentcitations
- 2020How Mn/Ni Ordering Controls Electrochemical Performance in High-Voltage Spinel LiNi0.44Mn1.56O4with Fixed Oxygen Contentcitations
- 2019Growth of multi-layered graphene on molybdenum catalyst by solid phase reaction with amorphous carboncitations
- 2014Highly protective performance of water-based epoxy coating loaded with self-doped nanopolyaniline synthesized under supercritical CO2 conditioncitations
- 2014Surface energy engineering for tunable wettability through controlled synthesis of MoS2citations
- 2013Large scale synthesis of single-crystal and polycrystalline boron nitride nanosheetscitations
- 2013Synthesis, characterization and understanding of the mechanisms of electroplating of nanocrystalline-amorphous nickel-tungsten alloys using in situ electrochemical impedance spectroscopycitations
- 2013Single-step route to hierarchical flower-like carbon nanotube clusters decorated with ultrananocrystalline diamondcitations
- 2012Water-soluble derivatives of octanuclear iron-oxido-pyrazolato complexes - An experimental and computational studycitations
- 2012Single-step route to diamond-nanotube compositecitations
Places of action
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article
Editors' Choice - Dealloying-Driven Cerium Precipitation on Intermetallic Particles in Aerospace Aluminium Alloys
Abstract
<p>Cerium-based compounds have been studied for decades as non-toxic candidates for the protection of aerospace aluminium alloys (AAs) like AA2024-T3. However, the complex heterogeneous microstructure of these alloys has hindered a thorough understanding of the subsequent stages of corrosion protection provided by this class of inhibitors. Thus, this work is devoted to unravelling the interaction mechanisms of different intermetallic particles (IMPs) in AA2024-T3 with cerium nitrate at the nanoscopic scale. This has been fulfilled through detailed top-view and cross-sectional analytical TEM investigations along with electrochemical evaluations. In line with our recent findings, we here report dealloying of IMPs as the main factor governing the rate of local cerium precipitation in contrast to micro-galvanic corrosion between IMPs and the surrounding matrix. Furthermore, we discuss a connection between the electrochemical response of the AA2024-T3 system and the morphological and compositional evolutions of individual IMPs including Al2CuMg, Al2Cu, Al7Cu2Fe(Mn) and Al76Cu6Fe7Mn5Si6 at different stages of a 96-h exposure.</p>