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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Kosari, Ali
Thermo Fisher Scientific (Netherlands)
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2022Evaluation of the formation and protectiveness of a lithium-based conversion layer using electrochemical noisecitations
- 2022Localised aqueous corrosion of electroless nickel immersion gold-coated coppercitations
- 2022Microstructure, mechanical, and corrosion properties of Zr1-xCrxBy diboride alloy thin films grown by hybrid high power impulse/DC magnetron co-sputteringcitations
- 2021Editors' Choice - Dealloying-Driven Cerium Precipitation on Intermetallic Particles in Aerospace Aluminium Alloyscitations
- 2021Nanoscopic and in-situ cross-sectional observations of Li-based conversion coating formation using liquid-phase TEMcitations
- 2021Laterally-resolved formation mechanism of a lithium-based conversion layer at the matrix and intermetallic particles in aerospace aluminium alloyscitations
- 2020Dealloying-driven local corrosion by intermetallic constituent particles and dispersoids in aerospace aluminium alloyscitations
- 2020In-situ nanoscopic observations of dealloying-driven local corrosion from surface initiation to in-depth propagationcitations
- 2020Cross-sectional characterization of the conversion layer formed on AA2024-T3 by a lithium-leaching coatingcitations
- 2020Corrosion resistance of hot-dip galvanized steel in simulated soil solutioncitations
- 2020Effect of simulated brazing on the microstructure and corrosion behavior of twin roll cast AA3003citations
- 2019Characterization of the passive layer on ferrite and austenite phases of super duplex stainless steelcitations
- 2019Effect of brazing on the microstructure and corrosion behaviour of a twin roll cast Al-Mn-Fe-Si alloy system
- 2018Enhanced corrosion protection of mild steel by the synergetic effect of zinc aluminum polyphosphate and 2-mercaptobenzimidazole inhibitors incorporated in epoxy-polyamide coatingscitations
Places of action
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article
Editors' Choice - Dealloying-Driven Cerium Precipitation on Intermetallic Particles in Aerospace Aluminium Alloys
Abstract
<p>Cerium-based compounds have been studied for decades as non-toxic candidates for the protection of aerospace aluminium alloys (AAs) like AA2024-T3. However, the complex heterogeneous microstructure of these alloys has hindered a thorough understanding of the subsequent stages of corrosion protection provided by this class of inhibitors. Thus, this work is devoted to unravelling the interaction mechanisms of different intermetallic particles (IMPs) in AA2024-T3 with cerium nitrate at the nanoscopic scale. This has been fulfilled through detailed top-view and cross-sectional analytical TEM investigations along with electrochemical evaluations. In line with our recent findings, we here report dealloying of IMPs as the main factor governing the rate of local cerium precipitation in contrast to micro-galvanic corrosion between IMPs and the surrounding matrix. Furthermore, we discuss a connection between the electrochemical response of the AA2024-T3 system and the morphological and compositional evolutions of individual IMPs including Al2CuMg, Al2Cu, Al7Cu2Fe(Mn) and Al76Cu6Fe7Mn5Si6 at different stages of a 96-h exposure.</p>