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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Gasteiger, Hubert A.
Technical University of Munich
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2023Catalyst Aggregate Size Effect on the Mass Transport Properties of Non-Noble Metal Catalyst Layers for PEMFC Cathodescitations
- 2022High Power Density Automotive Membrane Electrode Assemblies
- 2021Comparative Evaluation of LMR-NCM and NCA Cathode Active Materials in Multilayer Lithium-Ion Pouch Cells: Part I. Production, Electrode Characterization, and Formationcitations
- 2021Fluorination of Ni‐Rich lithium‐ion battery cathode materials by fluorine gas: chemistry, characterization, and electrochemical performance in full‐cellscitations
- 2020HOR Activity of Pt-TiO 2-Y at Unconventionally High Potentials Explained:The Influence of SMSI on the Electrochemical Behavior of Ptcitations
- 2019Editors' choice—understanding chemical stability issues between different solid electrolytes in all-solid-state batteries
- 2019Slurry-Based Processing of Solid Electrolytes: A Comparative Binder Study
- 2018Slurry-based processing of solid electrolytes: a comparative binder study
- 2018Lithium Bis(2,2,2-trifluoroethyl)phosphate Li[O2P(OCH2CF3)2]: a high voltage additive for LNMO/graphite cellscitations
- 2017Impact of microporous layer pore properties on liquid water transport in PEM fuel cells: carbon black type and perforation
- 2015ALD deposition of core-shell structures onto electrospun carbon webs for PEM fuel cell MEAs
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article
Comparative Evaluation of LMR-NCM and NCA Cathode Active Materials in Multilayer Lithium-Ion Pouch Cells: Part I. Production, Electrode Characterization, and Formation
Abstract
<jats:p>A lithium- and manganese-rich layered transition metal oxide (LMR-NCM) cathode active material (CAM) is processed on a pilot production line and assembled with graphite anodes to ≈7 Ah multilayer pouch cells. Each production step is outlined in detail and compared to NCA/graphite reference cells. Using laboratory coin cell data for different CAM loadings and cathode porosities, a simple calculation tool to extrapolate and optimize the energy density of multilayer pouch cells is presented and validated. Scanning electron microscopy and mercury porosimetry measurements of the cathodes elucidate the effect of the CAM morphology on the calendering process and explain the difficulty of achieving commonly used cathode porosities with LMR-NCM cathodes. Since LMR-NCMs exhibit strong gassing during the first cycles, a modified formation procedure based on on-line electrochemical mass spectroscopy is developed that allows stable cycling of LMR-NCM in multilayer pouch cells. After formation and degassing, LMR-NCM/graphite pouch cells have a 30% higher CAM-specific capacity and a ≈5%–10% higher cell-level energy density at a rate of C/10 compared to NCA/graphite cells. Rate capability, long-term cycling, and thermal behavior of the pouch cells in comparison with laboratory coin cells are investigated in Part II of this work.</jats:p>