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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Sharma, Neeraj
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2023Prospects of non-linear optical behaviour of PZT/ZnO heterostructurescitations
- 2022Qualitative analysis of PZT (52/48) MPB using different synthesis methodscitations
- 2022Importance of Superstructure in Stabilizing Oxygen Redox in P3-Na0.67Li0.2Mn0.8O2citations
- 2022Importance of superstructure in stabilizing oxygen redox in P3- Na0.67Li0.2Mn0.8O2citations
- 2022Importance of superstructure in stabilizing oxygen redox in P3- Na 0.67 Li 0.2 Mn 0.8 O 2citations
- 2021Importance of superstructure in stabilizing oxygen redox in P3- Na0.67Li0.2Mn0.8O2citations
- 2020In situ synchrotron XRD and sXAS studies on Li-S batteries with ionic-liquid and organic electrolytescitations
- 2020Multifunctional behavior of acceptor-cation substitution at higher doping concentration in PZT ceramicscitations
- 2019Multifunctional behavior of acceptor-cation substitution at higher doping concentration in PZT ceramicscitations
- 2019The Australian Battery Landscape
- 2018Structural evolution and stability of Sc 2 (WO 4 ) 3 after discharge in a sodium-based electrochemical cellcitations
- 2018From Lithium Metal to High Energy Batteries
- 2014Structural evolution of high energy density V3+/V4+ mixed valent Na3V2O2x(PO4)2F3−2x (x = 0.8) sodium vanadium fluorophosphate using in situ synchrotron X-ray powder diffractioncitations
- 2014Local structural changes in $LiMn_{1.5}Ni_{0.5}O_{4}$ spinel cathode material for lithium ion batteriescitations
- 2014A Mutagenic Primer Assay for Genotyping of the CRHR1 Gene Rare Variant rs1876828 (A/G) in Asians: A Cost-Effective SNP Typing.
Places of action
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article
In situ synchrotron XRD and sXAS studies on Li-S batteries with ionic-liquid and organic electrolytes
Abstract
Lithium-sulfur (Li-S) batteries are a promising technology capable of reaching high energy density of 500-700 Wh kg-1, however the practically achievable performance is still lower than this value. This hindrance can be attributed to a lack of understanding of the fundamental electrochemical processes during Li-S battery cycling, in particular the so-called redox shuttle effect which is due to the relatively high solubility of polysulfide intermediates in the electrolyte. Herein, the effects of LiNO3 as an additive as well as C4mpyr-based ionic liquids (ILs) in electrolyte formulations for Li-S cells are analysed using in situ X-ray powder diffraction (XRD) and ex situ soft X-ray absorption spectroscopy (sXAS) techniques. Whilst LiNO3 is known for its protective properties on the lithium anode in Li-S cells, our studies have provided further evidence for suppression of Li2S deposition when using LiNO3 as an additive, as well as affecting the solid electrolyte interphase (SEI) layer at a molecular level. Moreover, the detected sulfur species on the surface of the anode and cathode, after a few cycles are compared for IL and organic- based electrolytes.