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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Laplace, Annabelle
in Cooperation with on an Cooperation-Score of 37%
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Publications (7/7 displayed)
- 2024Process for incineration and in can vitrification: glass melt/liquid metal interactions and the multiphasic packagecitations
- 2023Glass formulation approach for mixed technological waste vitrification involving a rheological study of NCAS glasses
- 2023Study of the Crystallization in a Glass-Ceramic Sealcitations
- 2023Study of a glass-ceramic seal : porosity and sealing
- 2020Experimental and numerical investigations of an oxygen single‐bubble shrinkage in a borosilicate glass‐forming liquid doped with cerium oxidecitations
- 2017Hafnium solubility determination in soda-lime aluminosilicate glasscitations
- 2009Potentialities of fluoride-based salts for specific nuclear reprocessing: Overview of the R&D program at CEAcitations
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article
Study of the Crystallization in a Glass-Ceramic Seal
Abstract
<jats:p>Sealing is a major issue in Solid Oxide Cells (SOC) stacks used for hydrogen production. The specifications that seals must meet are particularly demanding. Glass-ceramics such as materials from the MgO-Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>-BaO-SiO<jats:sub>2</jats:sub>-B<jats:sub>2</jats:sub>O<jats:sub>3 </jats:sub>system are used. A preliminary treatment allows the initially amorphous material to set up while partially crystallizing. This paper presents the crystallization study of such a material. The main Ba<jats:sub>5</jats:sub>Si<jats:sub>8</jats:sub>O<jats:sub>21</jats:sub> and BaMg<jats:sub>2</jats:sub>Si<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub> crystalline phases are identified and the evolution of crystals morphology with the temperature is followed. The Ba<jats:sub>x</jats:sub>Si<jats:sub>y</jats:sub>O<jats:sub>x+2y </jats:sub>surface fraction is determined by image analysis as a function of time and temperature. These data allow accessing the equilibrium crystal fraction. It is then possible to optimize the crystallization treatment and to anticipate the microstructural evolution of the glass-ceramic seal operating in the stack.</jats:p>