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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Edwards, Danny J.
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Topics
Publications (5/5 displayed)
- 2022Interface effect of Fe and Fe<sub>2</sub>O<sub>3</sub> on the distributions of ion induced defectscitations
- 2010Degradation Mechanisms of SOFC Anodes in Coal Gas Containing Phosphoruscitations
- 2010Interaction of coal-derived synthesis gas impurities with solid oxide fuel cell metallic componentscitations
- 2010SOFC Ohmic Resistance Reduction by HCl-Induced Removal of Manganese at the Anode/Electrolyte Interfacecitations
- 2007Cleaning and passivation of copper surfaces to remove surface radioactivity and prevent oxide formationcitations
Places of action
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article
SOFC Ohmic Resistance Reduction by HCl-Induced Removal of Manganese at the Anode/Electrolyte Interface
Abstract
The ohmic resistance of anode-supported solid oxide fuel cells having a manganese-based cathode was lowered when operated in synthetic coal gas containing hydrogen chloride. This effect was not observed for cells with cathodes that did not contain manganese. Substantial amounts of Mn were found throughout the grain boundaries of the 8 mole% yttria-stabilized zirconia (8YSZ) electrolyte. Exposure to HCl partially removed Mn near the anode/electrolyte interface, presumably by volatilization as MnCl2(g). This work suggests that one of the underlying causes of higher than expected electrolyte resistance in anode-supported SOFCs is a lowering of the ionic conductivity of 8YSZ by incorporation of manganese.