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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Cramer, Carolyn N.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (5/5 displayed)
- 2010Advanced Ceramic Interconnect Material for Solid Oxide Fuel Cells: Electrical and Thermal Properties of Calcium- and Nickel-Doped Yttrium Chromitescitations
- 2010Calcium- and Cobalt-doped Yttrium Chromites as an Interconnect Material for Solid Oxide Fuel Cellscitations
- 2010Improvement of Sintering, Thermal Behavior, and Electrical Properties of Calcium- and Transition Metal-Doped Yttrium Chromitecitations
- 2010Interaction of coal-derived synthesis gas impurities with solid oxide fuel cell metallic componentscitations
- 2010SOFC Ohmic Resistance Reduction by HCl-Induced Removal of Manganese at the Anode/Electrolyte Interfacecitations
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article
SOFC Ohmic Resistance Reduction by HCl-Induced Removal of Manganese at the Anode/Electrolyte Interface
Abstract
The ohmic resistance of anode-supported solid oxide fuel cells having a manganese-based cathode was lowered when operated in synthetic coal gas containing hydrogen chloride. This effect was not observed for cells with cathodes that did not contain manganese. Substantial amounts of Mn were found throughout the grain boundaries of the 8 mole% yttria-stabilized zirconia (8YSZ) electrolyte. Exposure to HCl partially removed Mn near the anode/electrolyte interface, presumably by volatilization as MnCl2(g). This work suggests that one of the underlying causes of higher than expected electrolyte resistance in anode-supported SOFCs is a lowering of the ionic conductivity of 8YSZ by incorporation of manganese.