| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Gollas, Bernhard
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2023Unveiling the plating-stripping mechanism in aluminum batteries with imidazolium-based electrolytes:A hierarchical model based on experiments and ab initio simulationscitations
- 2023Unveiling the plating-stripping mechanism in aluminum batteries with imidazolium-based electrolytescitations
- 2022Dissolution and electrolysis of lunar regolith in ionic liquidscitations
- 2018The impact of operating conditions on component and electrode development for zinc-air flow batteriescitations
- 2018Mesostructure and physical properties of aqueous mixtures of the ionic liquid 1-ethyl-3-methyl imidazolium octyl sulfate doped with divalent sulfate salts in the liquid and the mesomorphic statescitations
- 2017Tin, bismuth, and tin–bismuth alloy electrodeposition from chlorometalate salts in deep eutectic solventscitations
- 2014Separation of 1,3-substituted imidazoles for quality control of a Lewis acidic ionic liquid for aluminum electroplatingcitations
- 2013Mechanistic Studies of Zinc Electrodeposition from Deep Eutectic Electrolytescitations
- 2011Preparation of CoNi high surface area porous foams by substrate controlled electrodepositioncitations
- 2010Zinc electrodeposition from a deep eutectic system containing choline chloride and ethylene glycolcitations
Places of action
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article
Zinc electrodeposition from a deep eutectic system containing choline chloride and ethylene glycol
Abstract
Deep eutectic electrolytes have recently been considered as alternatives to classical room-temperature ionic liquids. This work is an initial study of the zinc deposition process from a basic choline chloride/ethylene glycol deep eutectic solvent containing ZnCl 2 at 30°C. The system was examined by cyclic voltammetry at static and rotating glassy carbon disk electrodes and by potential step techniques. There was little deposition initially on sweeping or stepping the potential to ―0.5 to ―0.8 V vs Zn/Zn(II), but more rapid deposition was observed when the potential was subsequently raised to -0.4 to -0.2 V. The role of choline chloride was also studied by comparing with a choline-free electrolyte, which exhibited a more conventional voltammetric response. The formation of a dissolved, intermediate species Z on the cathodic sweep was proposed to account for the observed deposition behavior in the deep eutectic. Furthermore, an observation of the electrodeposition behavior with the addition of sodium ethoxide supports the suggestion that Z is a complex of Zn 2+ and deprotonated components of the solvent.