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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Mogensen, Mogens Bjerg
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (111/111 displayed)
- 2023Perovskite/Ruddlesden-Popper composite fuel electrode of strontium-praseodymium-manganese oxide for solid oxide cells: An alternative candidatecitations
- 2022Electrolytic deposition of reactive element thin films on Crofer 22 APU and evaluation of the resulting high-temperature corrosion protection properties at 700 °C – 900 °Ccitations
- 2021Ni migration in solid oxide cell electrodes: Review and revised hypothesiscitations
- 2020(Invited) Advanced Alkaline Electrolysis Cells for the Production of Sustainable Fuels and Chemicals
- 2020Review of Ni migration in SOC electrodes
- 2020Review of Ni migration in SOC electrodes
- 2019Influence of sintering profile on the microstructure and electronic transport properties of Sr(Ti,Nb)O3 tapes for solid oxide cell applications
- 2019Corrosion Study of Cr-Oxide Ceramics Using Rotating Ring Disk Electrode
- 2019Corrosion Study of Cr-Oxide Ceramics Using Rotating Ring Disk Electrode
- 2019Comprehensive Hypotheses for Degradation Mechanisms in Ni-Stabilized Zirconia Electrodescitations
- 2019Comprehensive Hypotheses for Degradation Mechanisms in Ni-Stabilized Zirconia Electrodescitations
- 2018Diffusion rates of reactants and components in solid oxide cells
- 2018Noise Phenomena in Electrochemical Impedance Spectroscopy of Polymer Electrolyte Membrane Electrolysis Cellscitations
- 2017Dynamic and Impure Perovskite Structured Metal Oxide Surfacescitations
- 2017Performance Improvement of an Inhomogeneous Cathode by Infiltrationcitations
- 2017Electrochemical Characterization of a PEMEC Using Impedance Spectroscopycitations
- 2017Effects of Gold Substrates on the Intrinsic and Extrinsic Activity of High-Loading Nickel-Based Oxyhydroxide Oxygen Evolution Catalystscitations
- 2017Chemical and Electrochemical Properties of La0.58Sr0.4Fe0.8Co0.2O3-δ (LSCF) Thin Films upon Oxygen Reduction and Evolution Reactions
- 2016Effects of strong cathodic polarization of the Ni-YSZ interfacecitations
- 2016Electrochemical Characterization of PEMECs Operating at Various Current Densities
- 2016Conductivity and structure of sub-micrometric SrTiO 3 -YSZ compositescitations
- 2016In-Situ Transmission Electron Microscopy on Operating Electrochemical Cells
- 2016Evolution of the electrochemical interface in high-temperature fuel cells and electrolyserscitations
- 2016New Hypothesis for SOFC Ceramic Oxygen Electrode Mechanismscitations
- 2016Conductivity and structure of sub-micrometric SrTiO3-YSZ compositescitations
- 2016High Temperature Alkaline Electrolysis Cells with Metal Foam Based Gas Diffusion Electrodescitations
- 2016Degradation of solid oxide cells during co-electrolysis of steam and carbon dioxide at high current densitiescitations
- 2015Size of oxide vacancies in fluorite and perovskite structured oxidescitations
- 2015Need for In Operando Characterization of Electrochemical Interface Features
- 2015Kinetics of CO/CO 2 and H 2 /H 2 O reactions at Ni-based and ceria-based solid-oxide-cell electrodescitations
- 2014Composite Fe - BaCe0.2Zr0.6Y0.2O2.9 Anodes for Proton Conductor Fuel Cellscitations
- 2014Electrochemical Characterization of Ni/ScYSZ Electrodes as SOFC Anodescitations
- 2014Composite Fe - BaCe 0.2 Zr 0.6 Y 0.2 O 2.9 Anodes for Proton Conductor Fuel Cellscitations
- 2014Power to fuel using electrolysis and CO2 capture
- 2014TOF-SIMS characterization of impurity enrichment and redistribution in solid oxide electrolysis cells during operationcitations
- 2014In situ surface reduction of a NiO-YSZ-alumina composite using scanning probe microscopycitations
- 2013Oxygen Electrode Kinetics and Surface Composition of Dense (La0.75Sr0.25)0.95MnO3 on YSZcitations
- 2013Pressurized HxCyOz Cells at ca. 250 °C: Potential and Challenges
- 2013Generalized trends in the formation energies of perovskite oxidescitations
- 2013Electrochemical reduction of CO 2 and H 2 O into fuels: Cell types and kinetic barriers
- 2013Ni-Based Solid Oxide Cell Electrodescitations
- 2013High temperature and pressure alkaline electrolysis
- 2013Electrochemical reduction of CO2 and H2O into fuels: Cell types and kinetic barriers
- 2013Alkaline electrolysis cell at high temperature and pressure of 250 °C and 42 barcitations
- 2013Pressurized H x C y O z Cells at ca. 250 °C: Potential and Challenges
- 2013Electrochemical reduction of NiO in a composite electrodecitations
- 2013Oxygen Electrode Kinetics and Surface Composition of Dense (La 0.75 Sr 0.25 ) 0.95 MnO 3 on YSZcitations
- 2012Energy, Environment and IMCCcitations
- 2012Composite Sr- and V-doped LaCrO 3 /YSZ sensor electrode operating at low oxygen levelscitations
- 2012Fundamental Material Properties Underlying Solid Oxide Electrochemistry
- 2012Durable and Robust Solid Oxide Fuel Cells
- 2012Composite Sr- and V-doped LaCrO3/YSZ sensor electrode operating at low oxygen levelscitations
- 2012Electrical conductivity of Ni–YSZ composites: Variants and redox cyclingcitations
- 2012Impact of Reduction Parameters on the Initial Performance and Stability of Ni/(Sc)YSZ Cermet Anodes for SOFCscitations
- 2011Planar metal-supported SOFC with novel cermet anodecitations
- 2011Planar metal-supported SOFC with novel cermet anodecitations
- 2011Electrical conductivity of Ni–YSZ composites: Degradation due to Ni particle growthcitations
- 2011Modifications of interface chemistry of LSM–YSZ composite by ceria nanoparticlescitations
- 2011SOFC LSM:YSZ cathode degradation induced by moisture: An impedance spectroscopy studycitations
- 2011Oxygen incorporation in porous thin films of strontium doped lanthanum ferritecitations
- 2010Characterization of (La 1-x Sr x )(s)MnO 3 and Doped Ceria Composite Electrodes in NO x -Containing Atmosphere with Impedance Spectroscopycitations
- 2010Solid Oxide Fuel Cell
- 2010Characterization of (La1-xSrx)(s)MnO3 and Doped Ceria Composite Electrodes in NOx-Containing Atmosphere with Impedance Spectroscopycitations
- 2010High Performance Fe-Co Based SOFC Cathodescitations
- 2010Ceria and strontium titanate based electrodes
- 2010Ceria and strontium titanate based electrodes
- 2010Defect structure, electronic conductivity and expansion of properties of (La1−xSrx)sCo1−yNiyO3−δcitations
- 2010Ni/YSZ electrode degradation studied by impedance spectroscopy: Effects of gas cleaning and current densitycitations
- 2010Continuum mechanics simulations of NiO/Ni-YSZ composites during reduction and re-oxidationcitations
- 2010Solid Oxide Fuel Cell:A method for producing a reversible solid oxid fuel cell
- 2010Atmosphere, temperature and pressure dependent segregation of bulk impurities in yttria-stabilized zirconia
- 2010The Effect of a CGO Barrier Layer on the Performance of LSM/YSZ SOFC Cathodescitations
- 2009Redox stability of SOFC: Thermal analysis of Ni-YSZ compositescitations
- 2009Electrochemical characterization and redox behavior of Nb-doped SrTiO 3citations
- 2009Mechanical properties of NiO/Ni-YSZ composites depending on temperature, porosity and redox cyclingcitations
- 2009Development of Planar Metal Supported SOFC with Novel Cermet Anodecitations
- 2009Development of Planar Metal Supported SOFC with Novel Cermet Anodecitations
- 2009Electrochemical characterization and redox behavior of Nb-doped SrTiO3citations
- 2008Effects of trace elements at the Ni/ScYSZ interface in a model solid oxide fuel cell anodecitations
- 2008Solid Oxide Electrolysis Cells: Microstructure and Degradation of the Ni/Yttria-Stabilized Zirconia Electrodecitations
- 2008Niobium-doped strontium titanates as SOFC anodes
- 2008Niobium-doped strontium titanates as SOFC anodes
- 2008Strontium Titanate-based Composite Anodes for Solid Oxide Fuel Cellscitations
- 2008Strontium Titanate-based Composite Anodes for Solid Oxide Fuel Cellscitations
- 2008Nanoscale chemical analysis and imaging of solid oxide cellscitations
- 2008Defect and electrical transport properties of Nb-doped SrTiO 3citations
- 2008Defect and electrical transport properties of Nb-doped SrTiO3citations
- 2007Synthesis of Nb-doped SrTiO 3 by a modified glycine-nitrate processcitations
- 2007Gd 0.6 Sr 0.4 Fe 0.8 Co 0.2 O 3-δ : A novel type of SOFC cathodecitations
- 2007Electrochemical Impedance Studies of SOFC Cathodescitations
- 2007Inter-diffusion between Co3O4 coatings and the oxide scale on Fe-22Crcitations
- 2007Inter-diffusion between Co 3 O 4 coatings and the oxide scale on Fe-22Crcitations
- 2007Synthesis of Nb-doped SrTiO3 by a modified glycine-nitrate processcitations
- 2007Gd0.6Sr0.4Fe0.8Co0.2O3-δ: A novel type of SOFC cathodecitations
- 2006Oxygen nonstoichiometry and transport properties of strontium substituted lanthanum cobaltitecitations
- 2006Electrode activation and passivation of solid oxide fuel cell electrodescitations
- 2006Break down of losses in thin electrolyte SOFCscitations
- 2005Characterization and microstructure of nanostructured LSM/YSZ composite cathode for high performance SOFC
- 2005Nanostructured lanthanum manganate composite cathodecitations
- 2004Factors controlling the oxide ion conductivity of fluorite and perovskite structured oxidescitations
- 2004The role of dopant concentration, A-site deficiency and processing on the electrical properties of strontium- and titanium-doped lanthanum scandatecitations
- 2003Studying the O 2 , metal/O 2- (solid electrolyte) electrode system with use of model electrodes: The exchange current density determinationcitations
- 2003Inter-Diffusion between NiO Coating and the Oxide Scale on Fe-22Cr Alloy
- 2003Effects of impurities of microstructure in Ni/YSZ-YSZ half-cells for SOFCcitations
- 2002Mixed conductor anodes: Ni as electrocatalyst for hydrogen conversioncitations
- 2001Microstructural and chemical changes at the Ni/YSZ interfacecitations
- 2001Effect of sintering temperature on microstructure and performance of LSM-YSZ composite cathodescitations
- 2001Effect of sintering temperature on microstructure and performance of LSM-YSZ composite cathodescitations
- 2001Correlation between impedance, activation energy and microstructure of composite (La 1 - x Sr x ) y MnO 3 ± δ /Zr 1 - z Y z O 2 - 0 . 5 z cathodes
- 2000Effect of electrode material on the oxidation of H2 at the metal-Sr0.995Ce0.95Y0.05O2.970 interfacecitations
- 2000Effect of electrode material on the oxidation of H 2 at the metal-Sr 0 . 9 9 5 Ce 0 . 9 5 Y 0 . 0 5 O 2 . 9 7 0 interfacecitations
Places of action
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article
Solid Oxide Electrolysis Cells: Microstructure and Degradation of the Ni/Yttria-Stabilized Zirconia Electrode
Abstract
Solid oxide fuel cells produced at Risø DTU have been tested as solid oxide electrolysis cells for steam electrolysis by applying an external voltage. Varying the sealing on the hydrogen electrode side of the setup verifies that the previously reported passivation over the first few hundred hours of electrolysis testing was an effect of the applied glass sealing. Degradation of the cells during long-term galvanostatic electrolysis testing [850°C, −1/2A/cm2, p(H2O)/p(H2)=0.5/0.5] was analyzed by impedance spectroscopy and the degradation was found mainly to be caused by increasing polarization resistance associated with thehydrogen electrode. A cell voltage degradation of 2%/1000h was obtained. Postmortem analysis of cells tested at these conditions showed that the electrode microstructure could withstand at least 1300h of electrolysis testing, however, impurities were found in the hydrogen electrode of tested solid oxide electrolysis cells. Electrolysis testing at high currentdensity, high temperature, and a high partial pressure of steam[−2A/cm2, 950°C, p(H2O)=0.9atm] was observed to lead to significant microstructural changes at the hydrogen electrode-electrolyte interface.