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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Hagen, Anke
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (30/30 displayed)
- 2024Fabrication framework for metal supported solid oxide cells via tape castingcitations
- 2024Fabrication framework for metal supported solid oxide cells via tape castingcitations
- 2024Reversible Operation of Metal Supported Solid Oxide Cellscitations
- 2023Performance and sulfur tolerance of a short stack with solid oxide cells using infiltrated strontium titanate based anodescitations
- 2023Low Temperature Performance and Durability of Solid Oxide Fuel Cells with Titanate Based Fuel Electrodes Using Reformate Fuelcitations
- 2022Metal Supported Electrolysis Cellscitations
- 2021Performance of Metal Supported SOFCs Operated in HydrocarbonFuels and at Low (>650 ˚C) Temperaturescitations
- 2020Co-electrolysis of steam and carbon dioxide in large area solid oxide cells based on infiltrated mesoporous oxygen electrodescitations
- 2020Metal Supported SOFCs for Mobile Applications using Hydrocarbon Fuelscitations
- 2019Developing Accelerated Stress Test Protocols for Solid Oxide Fuel Cells and Electrolysers: The European Project AD ASTRAcitations
- 2019Internal reforming on Metal supported SOFCscitations
- 2017Investigation of a Spinel-forming Cu-Mn Foam as an Oxygen Electrode Contact Material in a Solid Oxide Cell Single Repeating Unitcitations
- 2017Progress of SOFC/SOEC Development at DTU Energy: From Materials to Systemscitations
- 2016Performance Factors and Sulfur Tolerance of Metal Supported Solid Oxide Fuel Cells with Nanostructured Ni:GDC Infiltrated Anodescitations
- 2015Performance Factors and Sulfur Tolerance of Metal Supported Solid Oxide Fuel Cells with Nanostructured Ni:GDC Infiltrated Anodescitations
- 2013Defect chemistry, thermomechanical and transport properties of (RE2−xSrx)0.98(Fe0.8Co0.2)1−yMgyO4−δ (RE = La, Pr)citations
- 2013Defect chemistry, thermomechanical and transport properties of (RE 2 - x Sr x ) 0.98 (Fe 0.8 Co 0.2 ) 1 - y Mg y O 4 - δ (RE = La, Pr)citations
- 2012Durable and Robust Solid Oxide Fuel Cells
- 2012Test and Approval Center for Fuel Cell and Hydrogen Technologies: Phase I. Initiation
- 2010Defect Chemistry and Thermomechanical Properties of Ce0.8PrxTb0.2-xO2-deltacitations
- 2009Chromium poisoning of LSM/YSZ and LSCF/CGO composite cathodescitations
- 2009Status of Development and Manufacture of Solid Oxide Fuel Cell at Topsoe Fuel Cell A/S and Risø/DTUcitations
- 2009Status of Development and Manufacture of Solid Oxide Fuel Cell at Topsoe Fuel Cell A/S and Risø/DTUcitations
- 2008Assessment of the cathode contribution to the degradation of anode-supported solid oxide fuel cellscitations
- 2008Defect and electrical transport properties of Nb-doped SrTiO 3citations
- 2008Defect and electrical transport properties of Nb-doped SrTiO3citations
- 2008Defect and electrical transport properties of Nb-doped SrTiO3citations
- 2007Electrochemical Impedance Studies of SOFC Cathodescitations
- 2007Solid Oxide Fuel Cell Development at Topsoe Fuel Cell A/S and Risø National Laboratorycitations
- 2006Break down of losses in thin electrolyte SOFCscitations
Places of action
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article
Assessment of the cathode contribution to the degradation of anode-supported solid oxide fuel cells
Abstract
The degradation of anode-supported cells was studied over 1500 h as a function of cell polarization either in air or oxygen on the cathode side. Based on impedance analysis, contributions of the anode and cathode to the increase of total resistance were assigned. Accordingly, the degradation rates of the cathode were strongly dependent on the pO(2). Microstructural analysis of the cathode/electrolyte interface carried out after removal of the cathode showed craters on the electrolyte surface where the lanthanum strontium manganite (LSM) particles had been located. The changes of shape and size of these craters observed after testing correlated with the cell voltage degradation rates. The results can be interpreted in terms of element redistribution at the cathode/electrolyte interface and formation of foreign phases giving rise to a weakening of local contact points of the LSM cathode and yttria-stabilized zirconia electrolyte and consequently a reduced three-phase boundary length. (C) 2008 The Electrochemical Society.