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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Long, Jeffrey
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Publications (4/4 displayed)
- 2019(Keynote) Effect of Architecturally Expressed Electrodes and Catalysts on Energy Storage/Conversion in Aqueous Electrolytes
- 2018Formation of the layered conductive magnet CrCl2(pyrazine)2 through redox-active coordination chemistrycitations
- 2018Trapping a Ru2O3 Corundum-like Structure at Ultrathin, Disordered RuO2 Nanoskins Expressed in 3Dcitations
- 2008Self-Limiting Electropolymerization of o-Aminophenol on Ultraporous Carbon Nanoarchitectures for Electrochemical Capacitor Applicationscitations
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article
Self-Limiting Electropolymerization of o-Aminophenol on Ultraporous Carbon Nanoarchitectures for Electrochemical Capacitor Applications
Abstract
<jats:p>Electropolymerization of o-aminophenol at planar glassy carbonand ultraporous carbon nanofoam electrodes in buffered aqueouselectrolytes produces an ultrathin coating of poly(o-aminophenol), POAP.Poly(o-aminophenol) is not electroactiveat the deposition pH of 4.7, and thus the electrodeposited POAP film rapidly passivates the electrode surface against further monomer oxidation.The self-limiting nature of the depositionprocess allows ultrathin coatings to be deposited onto andwithin ultraporous electrode structures without occluding thethrough-connected pore network of the nanofoam.Whentransferred to acidic aqueous electrolytes, POAP protonates and becomes electroactive. The charge-storage capacity for theresulting composite POAP-coated carbon is higher than that forbare carbon because of the added faradaic electrochemicalreactions from the polymer coating.</jats:p>