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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bhagat, Rohit
Coventry University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2019Porous Metal-Organic Frameworks for Enhanced Performance Silicon Anodes in Lithium-Ion Batteriescitations
- 2019Temperature Considerations for Charging Li-Ion Batteriescitations
- 2018Binder-free Sn-Si heterostructure films for high capacity Li-ion batteriescitations
- 2018Electrochemical Evaluation and Phase-related Impedance Studies on Silicon-Few Layer Graphene (FLG) Composite Electrode Systemscitations
- 2017Electrodeposition of Si and Sn-based Amorphous Films for High Energy Novel Electrode Materialscitations
- 2017Investigation of cycling-induced microstructural degradation in silicon-based electrodes in lithium-ion batteries using X-ray nanotomographycitations
- 2016Metal recovery by electrodeposition from a molten salt two-phase cell systemcitations
- 2016Calculating the macroscopic dynamics of gas/metal/slag emulsion during steelmakingcitations
- 2015The Solubility of Specific Metal Oxides in Molten Borate Glasscitations
- 2013Precursor preparation for Ti-Al-V-Y alloy via FFC cambridge processcitations
- 2008Production of Ti-W alloys from mixed oxide precursors via the FFC cambridge processcitations
- 2008The production of Ti-Mo alloys from mixed oxide precursors via the FFC cambridge processcitations
- 2006Direct electrochemical production of Ti-10W alloys from mixed oxide preform precursorscitations
- 2005Direct electrochemical production of beta titanium alloys
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article
The production of Ti-Mo alloys from mixed oxide precursors via the FFC cambridge process
Abstract
Ti–15wt%Ti–15wt% Mo alloys were produced via the electrochemical deoxidation of (Ti,Mo)O2(Ti,Mo)O2 precursors (formed by sintering TiO2TiO2 and MoO2MoO2 blended powders) in a molten CaCl2CaCl2 electrolyte at 1173 K via the Fray–Farthing–Chen (FFC) Cambridge process. The reduction of (Ti,Mo)O2(Ti,Mo)O2 was characterized by analyzing several partially reduced samples taken periodically through the deoxidation process. Fully metallic samples were retrieved after 9 h of reduction. This relatively short reduction time relative to that documented in pure TiO2TiO2 was attributed to the early formation of a conductive (Ti,Mo)O2(Ti,Mo)O2 network. TiO2TiO2 is known to reduce through its lower oxides sequentially to form Ti. However, it was found that the presence of Mo reduced the number of lower Ti oxides traversed during reduction. This was believed to be beneficial as fewer crystallographic changes take place. The slowest step in the reduction of TiO2TiO2 is known to be the deoxidation of Ti; this step was accelerated as Mo stabilized β Ti at oxygen contents approaching TiO.