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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ritucci, Ilaria
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Development of glass sealants for proton conducting ceramic cells:materials, concepts and challengescitations
- 2022Fracture toughness of reactive bonded Co–Mn and Cu–Mn contact layers after long-term agingcitations
- 2022Torsional behaviour of a glass-ceramic joined alumina coated Crofer 22 APU steelcitations
- 2022Torsional behaviour of a glass-ceramic joined alumina coated Crofer 22 APU steelcitations
- 2022Torsional behaviour of a glass-ceramic joined alumina coated Crofer 22 APU steelcitations
- 2021High toughness well conducting contact layers for solid oxide cell stacks by reactive oxidative bondingcitations
- 2019Improving the interface adherence in solid oxide cell stacks:Glass seals and oxygen electrode contact layers
- 2018A Ba-free sealing glass with a high CTE and excellent interface stability optimized for SOFC/SOEC stack applicationscitations
- 2018A Ba-free sealing glass with a high CTE and excellent interface stability optimized for SOFC/SOEC stack applicationscitations
- 2017A Novel SOFC/SOEC Sealing Glass with a Low SiO2 Content and a High Thermal Expansion Coefficient
- 2017A Novel SOFC/SOEC Sealing Glass with a Low SiO2 Content and a High Thermal Expansion Coefficientcitations
- 2017A Novel SOFC/SOEC Sealing Glass with a Low SiO 2 Content and a High Thermal Expansion Coefficientcitations
Places of action
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article
A Novel SOFC/SOEC Sealing Glass with a Low SiO2 Content and a High Thermal Expansion Coefficient
Abstract
Solid oxide cells require seals that can function in harsh, elevated temperature environments. In addition, a low Si content can be advantageous, since Si impurities from the glass sealant can be transported to the active fuel electrode and poison the Ni-YSZ triple phase boundaries. To reduce the amount of Si emission, a low Si containing sealing glass (chemical composition: 50 mol% CaO, 20 mol% ZnO, 20 mol% B2O3 and 10 mol% SiO2) was developed at DTU. In this work, the results from thermal characterization, the crystallization behavior of the glass and the long-term stability and adhesion behavior of the glass were studied under SOFC and SOEC relevant conditions. The glass-ceramic sealant performed well over 400 h, and no cell degradation or leakage related to the seal was found, indicating that the developed glass system is applicable for the use in SOFC/SOEC stacks.