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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Boxall, Colin
Lancaster University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (26/26 displayed)
- 2022Corrosion Behaviour of AGR Simulated Fuels (SIMFUELs)
- 2019The behaviour of spent nuclear fuel in wet interim storage
- 2019Towards the decontamination of plutonium contaminated bricks
- 2018Mechanisms of fixed contamination of commonly engineered surfaces
- 2017Real time nanogravimetric monitoring of corrosion in radioactive environments
- 2017AGR Cladding Corrosioncitations
- 2016The effect of acetohydroxamic acid on stainless steel corrosion in nitric acidcitations
- 2016Real-Time Nanogravimetric Monitoring of Corrosion in Radioactive Decontamination Systemscitations
- 2016Corrosion of AGR Fuel Pin Steel Under Conditions Relevant to Permanent Disposalcitations
- 2015Corrosion behaviour of AGR SIMFUELScitations
- 2015The effect of SO3-Ph-BTBP on stainless steel corrosion in nitric acidcitations
- 2015Real time nanogravimetric monitoring of corrosion for nuclear decommissioningcitations
- 2013The metallisation of insulating substrates with nano-structured metal films of controllable pore dimensioncitations
- 2013The development of nanoporous metal membranes for analytical separartions
- 2013Nitric acid reduction on 316L stainless steel under conditions representative of reprocessingcitations
- 2013Corrosion behaviour of AGR simulated fuelscitations
- 2013The nanoporous metallisation of polymer membranes through photocatalytically initiated electroless depositioncitations
- 2012Method for formation of porous metal coatings
- 2012Surface Decontamination by Photocatalysis
- 2012The nanoporous metallisation of insulating substrates through Photocatalytically Initiated Electroless Deposition (PIED)
- 2012Semiconductor photocatalysis and metal deposition
- 2012Fixed Contamination on Steel Surfaces: First Use of Quartz Crystal Microgravimetry to Measure Oxide Growth on Process Steels Under Conditions Typical of Nuclear Reprocessingcitations
- 2010Surface decontamination by photocatalysis
- 2009Synthesis of alpha- and beta-FeOOH iron oxide nanoparticles in non-ionic surfactant mediumcitations
- 2006Mesoporous and Nanoparticulate Metal Oxides: Applications in New Photocatalysis
- 2005The applications of photocatalytic waste minimisation in nuclear fuel processingcitations
Places of action
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article
Corrosion behaviour of AGR simulated fuels
Abstract
We have prepared a range of Advanced Gas-cooled Reactor (AGR) SIMFUELs at a range of simulated burn-ups and, using Raman spectroscopy, have studied the effect of the SIMFUEL dopants on the UO2 crystal structure. We have also studied the effect of exposure to hydrogen peroxide solutions on the SIMFUEL surface. The intensity of the fundamental U-O stretch (445 cm-1) decreases as the amount of dopant increases in each SIMFUEL burn-up composition. A simultaneous increase in the lattice damage (500 – 700 cm-1) peak is observed as the UO2 cubic fluorite lattice structure becomes more distressed and moves towards a tetragonal structure. Exposure to 100 µmol dm-3 H2O2 further decreases the fundamental U-O stretch and increases the lattice damage peak, suggesting that additional point defects are established as the concentration of interstitial oxygen is increased in the lattice via the H2O2-induced corrosion of the SIMFUEL.