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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Kannan, R.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (6/6 displayed)
- 2023Operando neutron diffraction reveals mechanisms for controlled strain evolution in 3D printingcitations
- 2018Effect of Modified Nanoclay Composite on Blended PVDF/PEG Electrolyte Membranes for Fuel Cell Applicationscitations
- 2017Role of structural modifications of montmorillonite, electrical properties effect, physical behavior of nanocomposite proton conducting membranes for direct methanol fuel cell applicationscitations
- 2017Effect of target power on the physical properties of Ti thin films prepared by DC magnetron sputtering with supported dischargecitations
- 2016Facile synthesis and characterization of a reduced graphene oxide/halloysite nanotubes/hexagonal boron nitride (RGO/HNT/h-BN) hybrid nanocomposite and its potential application in hydrogen storagecitations
- 2014Effect of Substrate Bias Voltage on the Physical Properties of Zirconium Nitride (<font>ZrN</font>) Films Deposited by Mid Frequency Reactive Magnetron Sputteringcitations
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article
Effect of Modified Nanoclay Composite on Blended PVDF/PEG Electrolyte Membranes for Fuel Cell Applications
Abstract
<jats:p> This research work describes the fabrication of polymer blend nanocomposite membranes using the solution casting method. These membranes were fabricated with Poly (Vinylidene Fluoride) (PVdF) as host, Poly (Ethylene Glycol) (PEG) in steps of 2[Formula: see text]wt.% as blending polymer and Montmorillonite (MMT) nanoclay particles in steps of 3[Formula: see text]wt.% which were used as received. The protonated MMT was synthesized through an ion exchange process with column chromatographic technique. The prepared membrane’s performance was investigated using different characterization techniques of Thermo Gravimetric Analysis (TGA), Fourier Transform Infrared Spectroscopy (FT-IR), X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), water uptake, IEC and electrochemical impedance spectroscopy. Thermal stability was decreased while adding PEG into PVDF but it is controlled with the addition of MMT on PVDF/PEG blend matrix. Moreover, It is noticed that, the increase of water uptake, IEC by the increasing additive concentration of PEG and MMT. XRD studies reveal the increased amorphous phase with uniform exfoliation of nanoclay particles. The highest proton conductivity value of 0.127[Formula: see text]S cm[Formula: see text] is obtained with 9[Formula: see text]wt.% of MMT in the PVdF/PEG/MMT composite membranes at room temperature with 100% Relative Humid (RH) condition and 10 V.% of sulfonation. The blended nanocomposite membranes fulfill the requirements of proton exchange membrane for fuel cell application. </jats:p>