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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Liu, Ming
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2024High dielectric filler for all-solid-state lithium metal batterycitations
- 2023Discharge performance of a high temperature phase change material with low-cost wire meshcitations
- 2023Hydrophobized MFC as Reinforcing Additive in Industrial Silica/SBR Tire Tread Compoundcitations
- 2022Cage Molecules Stabilize Lead Halide Perovskite Thin Filmscitations
- 2021Chemical degradation in Thermally Cycled Stainless Steel 316 with High-Temperature Phase Change Materialcitations
- 2019Barely Porous Organic Cages for Hydrogen Isotope Separationcitations
- 2018Investigation into the behaviour of aluminium and steel under melt/freeze cyclic conditionscitations
- 2017A eutectic salt high temperature phase change material: Thermal stability and corrosion of SS316 with respect to thermal cyclingcitations
- 2016Stability and corrosion testing of a high temperature phase change material for CSP applicationscitations
- 2016Review on concentrating solar power plants and new developments in high temperature thermal energy storage technologiescitations
- 2015Atomic Layer Deposited Hybrid Organic-Inorganic Aluminates as Potential Low-k Dielectric Materialscitations
- 2010Electrochemical reactivity, surface composition and corrosion mechanisms of the complex metallic alloy Al 3 Mg 2citations
- 2010The influence of yttrium (Y) on the corrosion of Mg-Y binary alloyscitations
- 2009A preliminary quantitative XPS study of the surface films formed on pure magnesium and on magnesium-aluminium intermetallics by exposure to high-purity watercitations
- 2009A first quantitative XPS study of the surface films formed, by exposure to water, on Mg and on the Mg-Al intermetallics: Al 3 Mg 2 and Mg 17 Al 12citations
- 2009Calculated phase diagrams and the corrosion of die-cast Mg-Al alloyscitations
- 2008Calculated phase diagrams, iron tolerance limit, and corrosion of Mg-Al alloyscitations
Places of action
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article
Barely Porous Organic Cages for Hydrogen Isotope Separation
Abstract
The separation of hydrogen isotopes for applications such as nuclear fusion is a major challenge. Current technologies are energy intensive and inefficient. Nanoporous materials have the potential to separate hydrogen isotopes by kinetic quantum sieving, but high separation selectivity tends to correlate with low adsorption capacity, which can prohibit process scale-up. In this study, we use organic synthesis to modify the internal cavities of cage molecules to produce hybrid materials that are excellent quantum sieves. By combining small-pore and large-pore cages together in a single solid, we produce a material with optimal separation performance that combines an excellent deuterium/hydrogen selectivity (8.0) with a high deuterium uptake (4.7 millimoles per gram).