| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Hirscher, Michael
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2023Nanoporous adsorbents for hydrogen storagecitations
- 2022Magnesium- and intermetallic alloys-based hydrides for energy storage:Modelling, synthesis and propertiescitations
- 2022Magnesium- and intermetallic alloys-based hydrides for energy storage : modelling, synthesis and propertiescitations
- 2022Fundamentals of hydrogen storage in nanoporous materialscitations
- 2022Fundamentals of hydrogen storage in nanoporous materialscitations
- 2022Magnesium- and intermetallic alloys-based hydrides for energy storage: modelling, synthesis and properties ; ENEngelskEnglishMagnesium- and intermetallic alloys-based hydrides for energy storage: modelling, synthesis and propertiescitations
- 2022Magnesium- and intermetallic alloys-based hydrides for energy storage: modelling, synthesis and propertiescitations
- 2020Materials for hydrogen-based energy storage – past, recent progress and future outlookcitations
- 2019Barely Porous Organic Cages for Hydrogen Isotope Separationcitations
- 2014Highly effective hydrogen isotope separation in nanoporous metal-organic frameworks with open metal sitescitations
Places of action
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article
Barely Porous Organic Cages for Hydrogen Isotope Separation
Abstract
The separation of hydrogen isotopes for applications such as nuclear fusion is a major challenge. Current technologies are energy intensive and inefficient. Nanoporous materials have the potential to separate hydrogen isotopes by kinetic quantum sieving, but high separation selectivity tends to correlate with low adsorption capacity, which can prohibit process scale-up. In this study, we use organic synthesis to modify the internal cavities of cage molecules to produce hybrid materials that are excellent quantum sieves. By combining small-pore and large-pore cages together in a single solid, we produce a material with optimal separation performance that combines an excellent deuterium/hydrogen selectivity (8.0) with a high deuterium uptake (4.7 millimoles per gram).