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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Krekeler, Tobias
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (19/19 displayed)
- 2023Effect of Gd solutes on the micromechanical response of twinning and detwinning in Mgcitations
- 2023Wafer-Scale Fabrication of Hierarchically Porous Silicon and Silica Glass by Active Nanoparticle-Assisted Chemical Etching and Pseudomorphic Thermal Oxidationcitations
- 2023Magnetron Sputter Grown AlN Nanostructures with Giant Piezoelectric Response toward Energy Generationcitations
- 2023Magnetron Sputter Deposition of Nanostructured AlN Thin Filmscitations
- 2022Strengthening Engineered Nanocrystal Three-Dimensional Superlattices via Ligand Conformation and Reactivitycitations
- 2021Defects and plasticity in ultrastrong supercrystalline nanocompositescitations
- 2021Simultaneous enhancement of actuation strain and mechanical strength of nanoporous Ni–Mn actuatorscitations
- 2020Giant electrochemical actuation in a nanoporous silicon-polypyrrole hybrid materialcitations
- 2019Hierarchical supercrystalline nanocomposites through the self-assembly of organically-modified ceramic nanoparticlescitations
- 2019Hierarchical supercrystalline nanocomposites through the self-assembly of organically-modified ceramic nanoparticles
- 2019Hierarchical supercrystalline nanocomposites through the self-assembly of organically-modified ceramic nanoparticlescitations
- 2019Alumina-doped zirconia submicro-particles : synthesis, thermal stability, and microstructural characterizationcitations
- 2019Synthesis and thermal stability of ZrO2@SiO2 core-shell submicron particlescitations
- 2019Alumina-Doped Zirconia Submicro-Particles: Synthesis, Thermal Stability, and Microstructural Characterizationcitations
- 2019Modulating the Mechanical Properties of Supercrystalline Nanocomposite Materials via Solvent–Ligand Interactionscitations
- 2018Photonic materials for high-temperature applications: synthesis and characterization by X-ray ptychographic tomography
- 2017Semiordered hierarchical metallic network for fast and large charge-induced straincitations
- 2017Exceptionally strong, stiff and hard hybrid material based on an elastomer and isotropically shaped ceramic nanoparticlescitations
- 2017Highly porous α-Al 2 O 3 ceramics obtained by sintering atomic layer deposited inverse opals
Places of action
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article
Defects and plasticity in ultrastrong supercrystalline nanocomposites
Abstract
Supercrystalline nanocomposites are nanoarchitected materials with a growing range of applications but unexplored in their structural behavior. They typically consist of organically functionalized inorganic nanoparticles arranged into periodic structures analogous to crystalline lattices, including superlattice imperfections induced by processing or mechanical loading. Although featuring a variety of promising functional properties, their lack of mechanical robustness and unknown deformation mechanisms hamper their implementation into devices. We show that supercrystalline materials react to indentation with the same deformation patterns encountered in single crystals. Supercrystals accommodate plastic deformation in the form of pile-ups, dislocations, and slip bands. These phenomena occur, at least partially, also after cross-linking of the organic ligands, which leads to a multifold strengthening of the nanocomposites. The classic shear theories of crystalline materials are found to describe well the behavior of supercrystalline nanocomposites, which result to feature an elastoplastic behavior, accompanied by compaction.