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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Niss, Kristine
Roskilde University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2022Piezoelectric shear rheometrycitations
- 2018High-pressure cell for simultaneous dielectric and neutron spectroscopycitations
- 2017Coupling between Molecular Mobility and Kinetics of Crystal Growth in a Hydrogen-Bonded Liquidcitations
- 2017Connection between fragility, mean-squared displacement and shear modulus in two van der Waals bonded glass-forming liquidscitations
- 2015Communication: High pressure specific heat spectroscopy reveals simple relaxation behavior of glass forming molecular liquidcitations
- 2014The dynamic bulk modulus of three glass-forming liquidscitations
- 2005Dielectric and shear mechanical relaxations in glass-forming liquidscitations
Places of action
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article
Piezoelectric shear rheometry
Abstract
The piezoelectric shear gauge (PSG) [Christensen and Olsen, Rev. Sci. Instrum. 66, 5019 (1995)] is a rheometric technique developed to measure the complex shear modulus of viscous liquids near their glass transition temperature. We report recent advances to the PSG technique: (1) The data extraction procedure is optimized, which extends the upper limit of the frequency range of the method to between 50 and 70 kHz. (2) The measuring cell is simplified to use only one piezoelectric ceramic disk instead of three. We present an implementation of this design intended for liquid samples. Data obtained with this design revealed that a soft extra spacer is necessary to allow for thermal contraction of the sample in the axial direction. Model calculations show that flow in the radial direction is hindered by the confined geometry of the cell when the liquid becomes viscous upon cooling. The method is especially well-suited for—but not limited to—glassy materials.