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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Faul, Charl F. J.
University of Bristol
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Soft alchemycitations
- 2024Soft alchemy:a comprehensive guide to chemical reactions for pneumatic soft actuationcitations
- 2024Triphenylamine-Based Conjugated Microporous Polymers as the Next Generation Organic Cathode Materials
- 2023Electric Field-Driven Dielectrophoretic Elastomer Actuatorscitations
- 2021Efficient and Controlled Seeded Growth of Poly(3-hexylthiophene) Block Copolymer Nanofibers through Suppression of Homogeneous Nucleationcitations
- 2017Uniform “Patchy” Platelets by Seeded Heteroepitaxial Growth of Crystallizable Polymer Blends in Two Dimensionscitations
- 2016Influence of solvent polarity on the structure of drop-cast electroactive tetra(aniline)-surfactant thin filmscitations
- 2016Influence of solvent polarity on the structure of drop-cast electroactive tetra(aniline)-surfactant thin filmscitations
- 2016Biomimetic photo-actuationcitations
- 2015Self-assembly of a functional oligo(aniline)-based amphiphile into helical conductive nanowirescitations
- 2015Modelling and analysis of pH responsive hydrogels for the development of biomimetic photo-actuating structurescitations
- 2009Solid state nanofibers based on self-assemblies:from cleaving from self-assemblies to multilevel hierarchical constructscitations
Places of action
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document
Biomimetic photo-actuation
Abstract
Photo-actuation, such as that observed in the reversible sun-tracking movements of heliotropic plants, is produced by a complex, yet elegant series of processes. In the heliotropic leaf movements of the Cornish Mallow, photo-actuation involves the generation, transport and manipulation of chemical signals from a distributed network of sensors in the leaf veins to a specialized osmosis driven actuation region in the leaf stem. It is theorized that such an arrangement is both efficient in terms of materials use and operational energy conversion, as well as being highly robust. We concern ourselves with understanding and mimicking these light driven, chemically controlled actuating systems with the aim of generating intelligent structures which share the properties of efficiency and robustness that are so important to survival in Nature. In this work we present recent progress in mimicking these photo-actuating systems through remote light exposure of a metastable state photoacid and the resulting signal and energy transfer through solution to a pH-responsive hydrogel actuator. Reversible actuation strains of 20% were achieved from this arrangement, with modelling then employed to reveal the critical influence hydrogel pK<sub>a</sub> has on this result. Although the strong actuation achieved highlights the progress that has been made in replicating the principles of biomimetic photo-actuation, challenges such as photoacid degradation were also revealed. It is anticipated that current work can directly lead to the development of high-performance and low-cost solartrackers for increased photovoltaic energy capture and to the creation of new types of intelligent structures employing chemical control systems